Complexation of a polyelectrolyte with oppositely charged spherical macroions: Giant inversion of charge

T. T. Nguyen; B. I. Shklovskii

doi:10.1063/1.1355289

Complexation of a polyelectrolyte with oppositely charged spherical macroions: Giant inversion of charge

T. T. Nguyen, B. I. Shklovskii

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Abstract

The first theory of the sphere charge inversion (SCI) in the necklacelike complex of the polyelectrolyte (PE) with many spheres is proposed. This theory accounts for the interaction between different spheres. The theory, with minor modifications, can also describe the complexation of polyelectrolytes with macroions of nonspherical shape.

Original language	English (US)
Pages (from-to)	5905-5916
Number of pages	12
Journal	Journal of Chemical Physics
Volume	114
Issue number	13
DOIs	https://doi.org/10.1063/1.1355289
State	Published - Apr 1 2001

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10.1063/1.1355289

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abstract = "The first theory of the sphere charge inversion (SCI) in the necklacelike complex of the polyelectrolyte (PE) with many spheres is proposed. This theory accounts for the interaction between different spheres. The theory, with minor modifications, can also describe the complexation of polyelectrolytes with macroions of nonspherical shape.",

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AB - The first theory of the sphere charge inversion (SCI) in the necklacelike complex of the polyelectrolyte (PE) with many spheres is proposed. This theory accounts for the interaction between different spheres. The theory, with minor modifications, can also describe the complexation of polyelectrolytes with macroions of nonspherical shape.

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Complexation of a polyelectrolyte with oppositely charged spherical macroions: Giant inversion of charge

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