Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.
|Original language||English (US)|
|Number of pages||3|
|Journal||Bulletin of the Academy of Sciences of the USSR Division of Chemical Science|
|State||Published - Feb 1 1985|