Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

N. S. Zefirov; A. S. Koz'min; V. D. Sorokin; V. V. Zhdankin; Yu N. Studnev; A. V. Fokin

doi:10.1007/BF00951286

Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

N. S. Zefirov, A. S. Koz'min, V. D. Sorokin, V. V. Zhdankin, Yu N. Studnev, A. V. Fokin

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in Ad_E reactions.

Original language	English (US)
Pages (from-to)	356-358
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	34
Issue number	2
DOIs	https://doi.org/10.1007/BF00951286
State	Published - Feb 1 1985

Publisher link

10.1007/BF00951286

Find It

Find It at U of M Libraries

Cite this

@article{8d2c693ddb124296b0579f345ed2d5fa,

title = "Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins",

abstract = "Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.",

author = "Zefirov, {N. S.} and Koz'min, {A. S.} and Sorokin, {V. D.} and Zhdankin, {V. V.} and Studnev, {Yu N.} and Fokin, {A. V.}",

year = "1985",

month = feb,

day = "1",

doi = "10.1007/BF00951286",

language = "English (US)",

volume = "34",

pages = "356--358",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

publisher = "Springer New York",

number = "2",

}

TY - JOUR

T1 - Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

AU - Zefirov, N. S.

AU - Koz'min, A. S.

AU - Sorokin, V. D.

AU - Zhdankin, V. V.

AU - Studnev, Yu N.

AU - Fokin, A. V.

PY - 1985/2/1

Y1 - 1985/2/1

N2 - Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.

AB - Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.

UR - http://www.scopus.com/inward/record.url?scp=34250113503&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250113503&partnerID=8YFLogxK

U2 - 10.1007/BF00951286

DO - 10.1007/BF00951286

M3 - Article

AN - SCOPUS:34250113503

SN - 0568-5230

VL - 34

SP - 356

EP - 358

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 2

ER -

Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

Abstract

Publisher link

Find It

Other files and links

Fingerprint

Cite this