TY - JOUR
T1 - Comparative Study of Various Pyrazole-based Anions
T2 - A Promising Family of Ionic Derivatives as Insensitive Energetic Materials
AU - Yin, Ping
AU - Mitchell, Lauren A.
AU - Parrish, Damon A.
AU - Shreeve, Jean'ne M.
PY - 2017/2/1
Y1 - 2017/2/1
N2 - In the design of advanced energetic materials, high-density explosophores play a pivotal role because of their remarkable enhancement of both density and molecular stability. Using diversified functionalization strategies, a comparative study involving various nitropyrazole anions shows that these are crucially important in determining performance and stability. A promising family of pyrazole-based energetic ionic derivatives were synthesized and characterized by NMR and IR spectroscopies, and elemental analysis. Among them, 7, 8, 11–13 exhibit favorable overall performance as energetic materials.
AB - In the design of advanced energetic materials, high-density explosophores play a pivotal role because of their remarkable enhancement of both density and molecular stability. Using diversified functionalization strategies, a comparative study involving various nitropyrazole anions shows that these are crucially important in determining performance and stability. A promising family of pyrazole-based energetic ionic derivatives were synthesized and characterized by NMR and IR spectroscopies, and elemental analysis. Among them, 7, 8, 11–13 exhibit favorable overall performance as energetic materials.
KW - detonation properties
KW - energetic materials
KW - ionic derivatives
KW - nitrogen-rich compounds
KW - pyrazole-based anions
UR - http://www.scopus.com/inward/record.url?scp=85009486556&partnerID=8YFLogxK
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U2 - 10.1002/asia.201601615
DO - 10.1002/asia.201601615
M3 - Article
C2 - 28042911
AN - SCOPUS:85009486556
VL - 12
SP - 378
EP - 384
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
SN - 1861-4728
IS - 3
ER -