Co-pyrolysis of biomass and soapstock in a downdraft reactor using a novel ZSM-5/SiC composite catalyst

Lin Jiang; Yunpu Wang; Leilei Dai; Zhenting Yu; Qi Yang; Sha Yang; Deyu Jiang; Zhiyun Ma; Qiuhao Wu; Bo Zhang; Yuhuan Liu; Roger Ruan

doi:10.1016/j.biortech.2019.01.119

Co-pyrolysis of biomass and soapstock in a downdraft reactor using a novel ZSM-5/SiC composite catalyst

Lin Jiang, Yunpu Wang, Leilei Dai, Zhenting Yu, Qi Yang, Sha Yang, Deyu Jiang, Zhiyun Ma, Qiuhao Wu, Bo Zhang, Yuhuan Liu, Roger Ruan

Bioproducts and Biosystems Engineering

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A ZSM-5/SiC composite catalyst was synthesized and characterized by Brunauer–Emmett–Teller analysis, X-ray diffraction, and scanning electron microscopy in this study. The composite catalyst had the characteristics of ZSM-5 and SiC, and the surface of SiC grew evenly with a layer of ZSM-5. The effect of the composite catalyst on the product distribution and chemical composition in a co-pyrolysis downdraft system was investigated. In a down system with a catalytic temperature of 450 °C, a feed-to-catalyst ratio of 2:1, and a soybean-soapstock-to-straw ratio of 1:1, the proportions of alkanes, olefins, aromatics, and phenoxy compounds were 6.82%, 4.5%, 73.56% and 11.11%, respectively. The composite catalyst combined the catalytic performance of ZSM-5 and SiC, increasing the proportion of aromatics and decreasing the proportion of oxygen-containing compound in the bio-oil. Moreover, the composite catalyst maintained its activity after reusing several times.

Original language	English (US)
Pages (from-to)	202-208
Number of pages	7
Journal	Bioresource Technology
Volume	279
DOIs	https://doi.org/10.1016/j.biortech.2019.01.119
State	Published - May 2019

Bibliographical note

Funding Information:
This project is financially supported by the National Natural Science Foundation of China (No. 21766019 , No. 21878137 ), Key Research and Development Program of Jiangxi Province ( 20171BBF60023 ), Natural Science Foundation of Jiangxi Province ( 20181BAB206030 ), Research Project of State Key of Food Science and Technology ( SKLF-ZZB-201722 ), Science and Technology Research Project of Jiangxi Province Education Department (No. GJJ150213 ), Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (No. Y707sb1001 ), Innovation and Entrepreneurship Development Fund of “One Thousand Program” Talent (No. 1001-02102082 ).

Funding Information:
This project is financially supported by the National Natural Science Foundation of China (No. 21766019, No. 21878137), Key Research and Development Program of Jiangxi Province (20171BBF60023), Natural Science Foundation of Jiangxi Province (20181BAB206030), Research Project of State Key of Food Science and Technology (SKLF-ZZB-201722), Science and Technology Research Project of Jiangxi Province Education Department (No. GJJ150213), Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (No. Y707sb1001), Innovation and Entrepreneurship Development Fund of “One Thousand Program” Talent (No. 1001-02102082).

Publisher Copyright:
© 2019 Elsevier Ltd

Keywords

Co-pyrolysis
Composite catalyst
Downdraft system
SiC ceramic foam
ZSM-5

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10.1016/j.biortech.2019.01.119

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Co-pyrolysis of biomass and soapstock in a downdraft reactor using a novel ZSM-5/SiC composite catalyst. / Jiang, Lin; Wang, Yunpu; Dai, Leilei; Yu, Zhenting; Yang, Qi; Yang, Sha; Jiang, Deyu; Ma, Zhiyun; Wu, Qiuhao; Zhang, Bo; Liu, Yuhuan; Ruan, Roger.

In: Bioresource Technology, Vol. 279, 05.2019, p. 202-208.

Research output: Contribution to journal › Article › peer-review

@article{34dff3726c034a728933a9c7ec6533b6,

title = "Co-pyrolysis of biomass and soapstock in a downdraft reactor using a novel ZSM-5/SiC composite catalyst",

abstract = "A ZSM-5/SiC composite catalyst was synthesized and characterized by Brunauer–Emmett–Teller analysis, X-ray diffraction, and scanning electron microscopy in this study. The composite catalyst had the characteristics of ZSM-5 and SiC, and the surface of SiC grew evenly with a layer of ZSM-5. The effect of the composite catalyst on the product distribution and chemical composition in a co-pyrolysis downdraft system was investigated. In a down system with a catalytic temperature of 450 °C, a feed-to-catalyst ratio of 2:1, and a soybean-soapstock-to-straw ratio of 1:1, the proportions of alkanes, olefins, aromatics, and phenoxy compounds were 6.82%, 4.5%, 73.56% and 11.11%, respectively. The composite catalyst combined the catalytic performance of ZSM-5 and SiC, increasing the proportion of aromatics and decreasing the proportion of oxygen-containing compound in the bio-oil. Moreover, the composite catalyst maintained its activity after reusing several times.",

keywords = "Co-pyrolysis, Composite catalyst, Downdraft system, SiC ceramic foam, ZSM-5",

author = "Lin Jiang and Yunpu Wang and Leilei Dai and Zhenting Yu and Qi Yang and Sha Yang and Deyu Jiang and Zhiyun Ma and Qiuhao Wu and Bo Zhang and Yuhuan Liu and Roger Ruan",

note = "Funding Information: This project is financially supported by the National Natural Science Foundation of China (No. 21766019 , No. 21878137 ), Key Research and Development Program of Jiangxi Province ( 20171BBF60023 ), Natural Science Foundation of Jiangxi Province ( 20181BAB206030 ), Research Project of State Key of Food Science and Technology ( SKLF-ZZB-201722 ), Science and Technology Research Project of Jiangxi Province Education Department (No. GJJ150213 ), Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (No. Y707sb1001 ), Innovation and Entrepreneurship Development Fund of “One Thousand Program” Talent (No. 1001-02102082 ). Funding Information: This project is financially supported by the National Natural Science Foundation of China (No. 21766019, No. 21878137), Key Research and Development Program of Jiangxi Province (20171BBF60023), Natural Science Foundation of Jiangxi Province (20181BAB206030), Research Project of State Key of Food Science and Technology (SKLF-ZZB-201722), Science and Technology Research Project of Jiangxi Province Education Department (No. GJJ150213), Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (No. Y707sb1001), Innovation and Entrepreneurship Development Fund of “One Thousand Program” Talent (No. 1001-02102082). Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

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AU - Jiang, Lin

AU - Wang, Yunpu

AU - Dai, Leilei

AU - Yu, Zhenting

AU - Yang, Qi

AU - Yang, Sha

AU - Jiang, Deyu

AU - Ma, Zhiyun

AU - Wu, Qiuhao

AU - Zhang, Bo

AU - Liu, Yuhuan

AU - Ruan, Roger

N1 - Funding Information: This project is financially supported by the National Natural Science Foundation of China (No. 21766019 , No. 21878137 ), Key Research and Development Program of Jiangxi Province ( 20171BBF60023 ), Natural Science Foundation of Jiangxi Province ( 20181BAB206030 ), Research Project of State Key of Food Science and Technology ( SKLF-ZZB-201722 ), Science and Technology Research Project of Jiangxi Province Education Department (No. GJJ150213 ), Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (No. Y707sb1001 ), Innovation and Entrepreneurship Development Fund of “One Thousand Program” Talent (No. 1001-02102082 ). Funding Information: This project is financially supported by the National Natural Science Foundation of China (No. 21766019, No. 21878137), Key Research and Development Program of Jiangxi Province (20171BBF60023), Natural Science Foundation of Jiangxi Province (20181BAB206030), Research Project of State Key of Food Science and Technology (SKLF-ZZB-201722), Science and Technology Research Project of Jiangxi Province Education Department (No. GJJ150213), Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (No. Y707sb1001), Innovation and Entrepreneurship Development Fund of “One Thousand Program” Talent (No. 1001-02102082). Publisher Copyright: © 2019 Elsevier Ltd

PY - 2019/5

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N2 - A ZSM-5/SiC composite catalyst was synthesized and characterized by Brunauer–Emmett–Teller analysis, X-ray diffraction, and scanning electron microscopy in this study. The composite catalyst had the characteristics of ZSM-5 and SiC, and the surface of SiC grew evenly with a layer of ZSM-5. The effect of the composite catalyst on the product distribution and chemical composition in a co-pyrolysis downdraft system was investigated. In a down system with a catalytic temperature of 450 °C, a feed-to-catalyst ratio of 2:1, and a soybean-soapstock-to-straw ratio of 1:1, the proportions of alkanes, olefins, aromatics, and phenoxy compounds were 6.82%, 4.5%, 73.56% and 11.11%, respectively. The composite catalyst combined the catalytic performance of ZSM-5 and SiC, increasing the proportion of aromatics and decreasing the proportion of oxygen-containing compound in the bio-oil. Moreover, the composite catalyst maintained its activity after reusing several times.

AB - A ZSM-5/SiC composite catalyst was synthesized and characterized by Brunauer–Emmett–Teller analysis, X-ray diffraction, and scanning electron microscopy in this study. The composite catalyst had the characteristics of ZSM-5 and SiC, and the surface of SiC grew evenly with a layer of ZSM-5. The effect of the composite catalyst on the product distribution and chemical composition in a co-pyrolysis downdraft system was investigated. In a down system with a catalytic temperature of 450 °C, a feed-to-catalyst ratio of 2:1, and a soybean-soapstock-to-straw ratio of 1:1, the proportions of alkanes, olefins, aromatics, and phenoxy compounds were 6.82%, 4.5%, 73.56% and 11.11%, respectively. The composite catalyst combined the catalytic performance of ZSM-5 and SiC, increasing the proportion of aromatics and decreasing the proportion of oxygen-containing compound in the bio-oil. Moreover, the composite catalyst maintained its activity after reusing several times.

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KW - SiC ceramic foam

KW - ZSM-5

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Co-pyrolysis of biomass and soapstock in a downdraft reactor using a novel ZSM-5/SiC composite catalyst

Abstract

Bibliographical note

Keywords

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