Co-pyrolysis of biomass and soapstock in a downdraft reactor using a novel ZSM-5/SiC composite catalyst

Lin Jiang, Yunpu Wang, Leilei Dai, Zhenting Yu, Qi Yang, Sha Yang, Deyu Jiang, Zhiyun Ma, Qiuhao Wu, Bo Zhang, Yuhuan Liu, Roger Ruan

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A ZSM-5/SiC composite catalyst was synthesized and characterized by Brunauer–Emmett–Teller analysis, X-ray diffraction, and scanning electron microscopy in this study. The composite catalyst had the characteristics of ZSM-5 and SiC, and the surface of SiC grew evenly with a layer of ZSM-5. The effect of the composite catalyst on the product distribution and chemical composition in a co-pyrolysis downdraft system was investigated. In a down system with a catalytic temperature of 450 °C, a feed-to-catalyst ratio of 2:1, and a soybean-soapstock-to-straw ratio of 1:1, the proportions of alkanes, olefins, aromatics, and phenoxy compounds were 6.82%, 4.5%, 73.56% and 11.11%, respectively. The composite catalyst combined the catalytic performance of ZSM-5 and SiC, increasing the proportion of aromatics and decreasing the proportion of oxygen-containing compound in the bio-oil. Moreover, the composite catalyst maintained its activity after reusing several times.

Original languageEnglish (US)
Pages (from-to)202-208
Number of pages7
JournalBioresource Technology
Volume279
DOIs
StatePublished - May 2019

Bibliographical note

Funding Information:
This project is financially supported by the National Natural Science Foundation of China (No. 21766019 , No. 21878137 ), Key Research and Development Program of Jiangxi Province ( 20171BBF60023 ), Natural Science Foundation of Jiangxi Province ( 20181BAB206030 ), Research Project of State Key of Food Science and Technology ( SKLF-ZZB-201722 ), Science and Technology Research Project of Jiangxi Province Education Department (No. GJJ150213 ), Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (No. Y707sb1001 ), Innovation and Entrepreneurship Development Fund of “One Thousand Program” Talent (No. 1001-02102082 ).

Funding Information:
This project is financially supported by the National Natural Science Foundation of China (No. 21766019, No. 21878137), Key Research and Development Program of Jiangxi Province (20171BBF60023), Natural Science Foundation of Jiangxi Province (20181BAB206030), Research Project of State Key of Food Science and Technology (SKLF-ZZB-201722), Science and Technology Research Project of Jiangxi Province Education Department (No. GJJ150213), Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development (No. Y707sb1001), Innovation and Entrepreneurship Development Fund of “One Thousand Program” Talent (No. 1001-02102082).

Publisher Copyright:
© 2019 Elsevier Ltd

Keywords

  • Co-pyrolysis
  • Composite catalyst
  • Downdraft system
  • SiC ceramic foam
  • ZSM-5

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