Abstract
A study was performed on classical Wigner phase space approximation to cumulative matrix elements in coherent control. It was found that the classical limit of the Wigner-Weyl representation was used to approximate products of bound-continuum matrix elements. The range of utility of the method was quantified through an examination of model problems, multiarrangement channel photodissociation of CH2IBr and single-channel Na2 dissociation.
Original language | English (US) |
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Pages (from-to) | 3606-3618 |
Number of pages | 13 |
Journal | Journal of Chemical Physics |
Volume | 119 |
Issue number | 7 |
DOIs | |
State | Published - Aug 15 2003 |