Chromatographic Evaluation of Porous Carbon-Clad Zirconia Microparticles

Thomas P. Weber, Paul T. Jackson, Peter W Carr

Research output: Contribution to journalArticlepeer-review

73 Scopus citations

Abstract

The chemical vapor deposition of hydrocarbons on porous zirconia (Z1O2) microparticles creates a reversed-phase support that is significantly different from conventional bonded reversed-phase supports. This carbon-overlaid zirconia support (C/Z1O2) is stable to conditions of extreme pH (0-12) and temperature (80 °C). It differs greatly from conventional supports in its chromatographic selectivity; the separation of positional isomers is facile, and they are well resolved compared to the separation on ODS silica. The unique chromatographic nature of this material was studied in detail to better understand and find applications for this novel stationary phase. The results of loading capacity and chromatographic efficiency studies are also discussed.

Original languageEnglish (US)
Pages (from-to)3042-3050
Number of pages9
JournalAnalytical chemistry
Volume67
Issue number17
DOIs
StatePublished - Jan 1 1995

Fingerprint Dive into the research topics of 'Chromatographic Evaluation of Porous Carbon-Clad Zirconia Microparticles'. Together they form a unique fingerprint.

Cite this