Chemoselectivity in catalytic C-C and C-H bond activation: Controlling intermolecular carboacylation and hydroarylation of alkenes

Michael T. Wentzel; Venkata Jaganmohan Reddy; Todd K. Hyster; Christopher J Douglas

doi:10.1002/anie.200902215

Chemoselectivity in catalytic C-C and C-H bond activation: Controlling intermolecular carboacylation and hydroarylation of alkenes

Michael T. Wentzel, Venkata Jaganmohan Reddy, Todd K. Hyster, Christopher J Douglas

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

119 Scopus citations

Abstract

It's all under control: The selection between C-C and C-H activation pathways in 8-acylquinolines can be influenced by the choice of catalyst and solvent (see scheme; cod=cycloocta-1,5-diene). In this approach, an unstrained C-C σ bond is activated and subsequent intermolecular carboacylation of an olefin results in the formation of two new C-C σ bonds.

Original language	English (US)
Pages (from-to)	6121-6123
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	33
DOIs	https://doi.org/10.1002/anie.200902215
State	Published - Oct 19 2009

Keywords

C-C activation
C-H activation
Chemoselectivity
Homogeneous catalysis
Rhodium

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10.1002/anie.200902215

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abstract = "It's all under control: The selection between C-C and C-H activation pathways in 8-acylquinolines can be influenced by the choice of catalyst and solvent (see scheme; cod=cycloocta-1,5-diene). In this approach, an unstrained C-C σ bond is activated and subsequent intermolecular carboacylation of an olefin results in the formation of two new C-C σ bonds.",

keywords = "C-C activation, C-H activation, Chemoselectivity, Homogeneous catalysis, Rhodium",

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AU - Reddy, Venkata Jaganmohan

AU - Hyster, Todd K.

AU - Douglas, Christopher J

PY - 2009/10/19

Y1 - 2009/10/19

N2 - It's all under control: The selection between C-C and C-H activation pathways in 8-acylquinolines can be influenced by the choice of catalyst and solvent (see scheme; cod=cycloocta-1,5-diene). In this approach, an unstrained C-C σ bond is activated and subsequent intermolecular carboacylation of an olefin results in the formation of two new C-C σ bonds.

AB - It's all under control: The selection between C-C and C-H activation pathways in 8-acylquinolines can be influenced by the choice of catalyst and solvent (see scheme; cod=cycloocta-1,5-diene). In this approach, an unstrained C-C σ bond is activated and subsequent intermolecular carboacylation of an olefin results in the formation of two new C-C σ bonds.

KW - C-C activation

KW - C-H activation

KW - Chemoselectivity

KW - Homogeneous catalysis

KW - Rhodium

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Chemoselectivity in catalytic C-C and C-H bond activation: Controlling intermolecular carboacylation and hydroarylation of alkenes

Abstract

Keywords

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