Characterization of pentacarbonylvanadate(−iii) and hydridopentacarbonyl- vanadate(−ii) by13C,51V, and1H n.m.r. spectroscopy

Garry F.P. Warnock; Stephen B. Philson; John E. Ellis

doi:10.1039/C39840000893

Characterization of pentacarbonylvanadate(−iii) and hydridopentacarbonyl- vanadate(−ii) by¹³C,⁵¹V, and¹H n.m.r. spectroscopy

Garry F.P. Warnock, Stephen B. Philson, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

N.m.r. spectra of highly reduced vanadium carbonyls containing 99% enriched¹³CO in liquid ammonia at −50 °C provide the first direct spectroscopic evidence for the existence of Na₃[V(CO)₅] and Na₂[HV(CO)₅] in solution.

Original language	English (US)
Pages (from-to)	893-894
Number of pages	2
Journal	Journal of the Chemical Society - Series Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/C39840000893
State	Published - 1984

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title = "Characterization of pentacarbonylvanadate(−iii) and hydridopentacarbonyl- vanadate(−ii) by13C,51V, and1H n.m.r. spectroscopy",

abstract = "N.m.r. spectra of highly reduced vanadium carbonyls containing 99% enriched13CO in liquid ammonia at −50 °C provide the first direct spectroscopic evidence for the existence of Na3[V(CO)5] and Na2[HV(CO)5] in solution.",

author = "Warnock, {Garry F.P.} and Philson, {Stephen B.} and Ellis, {John E.}",

year = "1984",

doi = "10.1039/C39840000893",

language = "English (US)",

pages = "893--894",

journal = "Journal of the Chemical Society - Series Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "14",

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T1 - Characterization of pentacarbonylvanadate(−iii) and hydridopentacarbonyl- vanadate(−ii) by13C,51V, and1H n.m.r. spectroscopy

AU - Warnock, Garry F.P.

AU - Philson, Stephen B.

AU - Ellis, John E.

PY - 1984

Y1 - 1984

N2 - N.m.r. spectra of highly reduced vanadium carbonyls containing 99% enriched13CO in liquid ammonia at −50 °C provide the first direct spectroscopic evidence for the existence of Na3[V(CO)5] and Na2[HV(CO)5] in solution.

AB - N.m.r. spectra of highly reduced vanadium carbonyls containing 99% enriched13CO in liquid ammonia at −50 °C provide the first direct spectroscopic evidence for the existence of Na3[V(CO)5] and Na2[HV(CO)5] in solution.

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DO - 10.1039/C39840000893

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AN - SCOPUS:37049111825

SN - 0022-4936

SP - 893

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JO - Journal of the Chemical Society - Series Chemical Communications

JF - Journal of the Chemical Society - Series Chemical Communications

IS - 14

ER -

Characterization of pentacarbonylvanadate(−iii) and hydridopentacarbonyl- vanadate(−ii) by¹³C,⁵¹V, and¹H n.m.r. spectroscopy

Abstract

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