Characterization of pentacarbonylvanadate(−iii) and hydridopentacarbonyl- vanadate(−ii) by13C,51V, and1H n.m.r. spectroscopy

Garry F.P. Warnock, Stephen B. Philson, John E. Ellis

Research output: Contribution to journalArticle

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Abstract

N.m.r. spectra of highly reduced vanadium carbonyls containing 99% enriched13CO in liquid ammonia at −50 °C provide the first direct spectroscopic evidence for the existence of Na3[V(CO)5] and Na2[HV(CO)5] in solution.

Original languageEnglish (US)
Pages (from-to)893-894
Number of pages2
JournalJournal of the Chemical Society - Series Chemical Communications
Issue number14
DOIs
StatePublished - Jan 1 1984

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