Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

David P. De Sousa; Jennifer O. Bigelow; Jonas Sundberg; Lawrence Que; Christine J. McKenzie

doi:10.1039/c4cc08785b

Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

David P. De Sousa
, Jennifer O. Bigelow
, Jonas Sundberg
, Lawrence Que
, Christine J. McKenzie

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

A Cr(iv)η²-peroxo complex crystallizes from 33% aqueous H₂O₂. The complex is a likely intermediate in catalytic disproportionation of H₂O₂ proposed to occur through a single metal site mechanism in solution-and solid state.

Original language	English (US)
Pages (from-to)	2802-2805
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	14
DOIs	https://doi.org/10.1039/c4cc08785b
State	Published - Feb 18 2015

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© The Royal Society of Chemistry 2015.

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10.1039/c4cc08785b

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title = "Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)",

abstract = "A Cr(iv)η2-peroxo complex crystallizes from 33\% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution-and solid state.",

author = "\{De Sousa\}, \{David P.\} and Bigelow, \{Jennifer O.\} and Jonas Sundberg and Lawrence Que and McKenzie, \{Christine J.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = feb,

day = "18",

doi = "10.1039/c4cc08785b",

language = "English (US)",

volume = "51",

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journal = "Chemical Communications",

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T1 - Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

AU - De Sousa, David P.

AU - Bigelow, Jennifer O.

AU - Sundberg, Jonas

AU - Que, Lawrence

AU - McKenzie, Christine J.

PY - 2015/2/18

Y1 - 2015/2/18

N2 - A Cr(iv)η2-peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution-and solid state.

AB - A Cr(iv)η2-peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution-and solid state.

UR - https://www.scopus.com/pages/publications/84922347787

UR - https://www.scopus.com/pages/publications/84922347787#tab=citedBy

U2 - 10.1039/c4cc08785b

DO - 10.1039/c4cc08785b

M3 - Article

C2 - 25583254

AN - SCOPUS:84922347787

SN - 1359-7345

VL - 51

SP - 2802

EP - 2805

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

Abstract

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