Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

David P. De Sousa, Jennifer O. Bigelow, Jonas Sundberg, Lawrence Que, Christine J. McKenzie

Research output: Contribution to journalArticle

13 Scopus citations

Abstract

A Cr(iv)η2-peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution-and solid state.

Original languageEnglish (US)
Pages (from-to)2802-2805
Number of pages4
JournalChemical Communications
Volume51
Issue number14
DOIs
StatePublished - Feb 18 2015

Fingerprint Dive into the research topics of 'Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)'. Together they form a unique fingerprint.

  • Cite this

    De Sousa, D. P., Bigelow, J. O., Sundberg, J., Que, L., & McKenzie, C. J. (2015). Caught! Crystal trapping of a side-on peroxo bound to Cr(IV). Chemical Communications, 51(14), 2802-2805. https://doi.org/10.1039/c4cc08785b