Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

David P. De Sousa; Jennifer O. Bigelow; Jonas Sundberg; Lawrence Que; Christine J. McKenzie

doi:10.1039/c4cc08785b

Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

David P. De Sousa, Jennifer O. Bigelow, Jonas Sundberg, Lawrence Que, Christine J. McKenzie

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A Cr(iv)η²-peroxo complex crystallizes from 33% aqueous H₂O₂. The complex is a likely intermediate in catalytic disproportionation of H₂O₂ proposed to occur through a single metal site mechanism in solution-and solid state.

Original language	English (US)
Pages (from-to)	2802-2805
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	14
DOIs	https://doi.org/10.1039/c4cc08785b
State	Published - Feb 18 2015

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© The Royal Society of Chemistry 2015.

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title = "Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)",

abstract = "A Cr(iv)η2-peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution-and solid state.",

author = "{De Sousa}, {David P.} and Bigelow, {Jennifer O.} and Jonas Sundberg and Lawrence Que and McKenzie, {Christine J.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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doi = "10.1039/c4cc08785b",

language = "English (US)",

volume = "51",

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AU - De Sousa, David P.

AU - Bigelow, Jennifer O.

AU - Sundberg, Jonas

AU - Que, Lawrence

AU - McKenzie, Christine J.

PY - 2015/2/18

Y1 - 2015/2/18

N2 - A Cr(iv)η2-peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution-and solid state.

AB - A Cr(iv)η2-peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution-and solid state.

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

Abstract

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