Carboxylatoiron(II) Aggregates: A Novel Fe 4II Complex with Threefold Symmetry

Stéphane Ménage; Hiroshi Fujii; Michael P. Hendrich; Lawrence Que

doi:10.1002/anie.199416601

Carboxylatoiron(II) Aggregates: A Novel Fe 4II Complex with Threefold Symmetry

Stéphane Ménage
, Hiroshi Fujii
, Michael P. Hendrich
, Lawrence Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

One monodentate and two bidentate carboxylato ligands link the central Fe^II ion in the cation of 1 (shown on the right) with each of the three neighboring Fe^II ions. This arrangement results in a complex with threefold symmetry and weak ferromagnetic interactions between the iron centers. Such aggregates may be important in the initial stages of ferritin core formation in the absence of dioxygen. Hbpg = N,N‐bis(2‐pyridylmethyl)glycine. (Formula Presented.) (Figure Presented.)

Original language	English (US)
Pages (from-to)	1660-1662
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	33
Issue number	15-16
DOIs	https://doi.org/10.1002/anie.199416601
State	Published - Sep 2 1994

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10.1002/anie.199416601

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title = "Carboxylatoiron(II) Aggregates: A Novel Fe 4II Complex with Threefold Symmetry",

abstract = "One monodentate and two bidentate carboxylato ligands link the central FeII ion in the cation of 1 (shown on the right) with each of the three neighboring FeII ions. This arrangement results in a complex with threefold symmetry and weak ferromagnetic interactions between the iron centers. Such aggregates may be important in the initial stages of ferritin core formation in the absence of dioxygen. Hbpg = N,N‐bis(2‐pyridylmethyl)glycine. (Formula Presented.) (Figure Presented.)",

author = "St{\'e}phane M{\'e}nage and Hiroshi Fujii and Hendrich, \{Michael P.\} and Lawrence Que",

year = "1994",

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doi = "10.1002/anie.199416601",

language = "English (US)",

volume = "33",

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journal = "Angewandte Chemie International Edition in English",

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T1 - Carboxylatoiron(II) Aggregates

T2 - A Novel Fe 4II Complex with Threefold Symmetry

AU - Ménage, Stéphane

AU - Fujii, Hiroshi

AU - Hendrich, Michael P.

AU - Que, Lawrence

PY - 1994/9/2

Y1 - 1994/9/2

N2 - One monodentate and two bidentate carboxylato ligands link the central FeII ion in the cation of 1 (shown on the right) with each of the three neighboring FeII ions. This arrangement results in a complex with threefold symmetry and weak ferromagnetic interactions between the iron centers. Such aggregates may be important in the initial stages of ferritin core formation in the absence of dioxygen. Hbpg = N,N‐bis(2‐pyridylmethyl)glycine. (Formula Presented.) (Figure Presented.)

AB - One monodentate and two bidentate carboxylato ligands link the central FeII ion in the cation of 1 (shown on the right) with each of the three neighboring FeII ions. This arrangement results in a complex with threefold symmetry and weak ferromagnetic interactions between the iron centers. Such aggregates may be important in the initial stages of ferritin core formation in the absence of dioxygen. Hbpg = N,N‐bis(2‐pyridylmethyl)glycine. (Formula Presented.) (Figure Presented.)

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UR - https://www.scopus.com/pages/publications/33751126816#tab=citedBy

U2 - 10.1002/anie.199416601

DO - 10.1002/anie.199416601

M3 - Article

AN - SCOPUS:33751126816

SN - 0570-0833

VL - 33

SP - 1660

EP - 1662

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 15-16

ER -

Carboxylatoiron(II) Aggregates: A Novel Fe 4II Complex with Threefold Symmetry

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