Carbonylative enantioselective meso-desymmetrization of cis-epoxides to trans-β-lactones: Effect of salen-ligand electronic variation on enantioselectivity

Michael Mulzer; Jessica R. Lamb; Zachary Nelson; Geoffrey W. Coates

doi:10.1039/c4cc04397a

Carbonylative enantioselective meso-desymmetrization of cis-epoxides to trans-β-lactones: Effect of salen-ligand electronic variation on enantioselectivity

Michael Mulzer
, Jessica R. Lamb
, Zachary Nelson
, Geoffrey W. Coates

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The deprotection of a common precursor moiety in dithiolene chemistry was discovered to be fully reversible, which, besides being relevant for researchers working in very different fields with these non-innocent ligand systems, may even have an impact on CO₂ housekeeping, as the deprotected ligand acts as an efficient trap.

Original language	English (US)
Pages (from-to)	9842-9845
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	69
DOIs	https://doi.org/10.1039/c4cc04397a
State	Published - Jul 31 2014
Externally published	Yes

Publisher link

10.1039/c4cc04397a

Find It

Find It at U of M Libraries

Cite this

@article{1d1072c502cd47a4a4f32fde469a3a1a,

title = "Carbonylative enantioselective meso-desymmetrization of cis-epoxides to trans-β-lactones: Effect of salen-ligand electronic variation on enantioselectivity",

abstract = "The deprotection of a common precursor moiety in dithiolene chemistry was discovered to be fully reversible, which, besides being relevant for researchers working in very different fields with these non-innocent ligand systems, may even have an impact on CO2 housekeeping, as the deprotected ligand acts as an efficient trap.",

author = "Michael Mulzer and Lamb, \{Jessica R.\} and Zachary Nelson and Coates, \{Geoffrey W.\}",

year = "2014",

month = jul,

day = "31",

doi = "10.1039/c4cc04397a",

language = "English (US)",

volume = "50",

pages = "9842--9845",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "69",

}

TY - JOUR

T1 - Carbonylative enantioselective meso-desymmetrization of cis-epoxides to trans-β-lactones

T2 - Effect of salen-ligand electronic variation on enantioselectivity

AU - Mulzer, Michael

AU - Lamb, Jessica R.

AU - Nelson, Zachary

AU - Coates, Geoffrey W.

PY - 2014/7/31

Y1 - 2014/7/31

N2 - The deprotection of a common precursor moiety in dithiolene chemistry was discovered to be fully reversible, which, besides being relevant for researchers working in very different fields with these non-innocent ligand systems, may even have an impact on CO2 housekeeping, as the deprotected ligand acts as an efficient trap.

AB - The deprotection of a common precursor moiety in dithiolene chemistry was discovered to be fully reversible, which, besides being relevant for researchers working in very different fields with these non-innocent ligand systems, may even have an impact on CO2 housekeeping, as the deprotected ligand acts as an efficient trap.

UR - https://www.scopus.com/pages/publications/84905455041

UR - https://www.scopus.com/pages/publications/84905455041#tab=citedBy

U2 - 10.1039/c4cc04397a

DO - 10.1039/c4cc04397a

M3 - Article

AN - SCOPUS:84905455041

SN - 1359-7345

VL - 50

SP - 9842

EP - 9845

JO - Chemical Communications

JF - Chemical Communications

IS - 69

ER -

Carbonylative enantioselective meso-desymmetrization of cis-epoxides to trans-β-lactones: Effect of salen-ligand electronic variation on enantioselectivity

Abstract

Publisher link

Find It

Other files and links

Fingerprint

Cite this