Can an ancillary ligand lead to a thermodynamically stable end-on 1: 1 Cu-O₂ adduct supported by a β-diketiminate ligand?

Keyphrases

• Dioxygen 100%
• Thermodynamically Stable 100%
• Diketiminate 100%
• Ancillary Ligand 100%
• Hydrogen Donor 50%
• Sterically Hindered 25%
• Density Functional Theory 25%
• Isomerization 25%
• N-heterocyclic Carbenes 25%
• Model Complex 25%
• Phosphine 25%
• Monooxygenase 25%
• Acetonitrile 25%
• Electron-donating 25%
• Oxygenation 25%
• Thiophene 25%
• Pyridine N 25%
• Five-membered Rings 25%
• Unstable Intermediates 25%
• Cyclic Ethers 25%
• Substituted Pyridines 25%
• Potential Hydrogen 25%
• Steric Bulk 25%
• Biomimetic Models 25%
• Oxygenation Mechanism 25%
• Work Density 25%
• N-heterocyclic Ligands 25%
• Bulky Ligands 25%
• Multireference Methods 25%

Biochemistry, Genetics and Molecular Biology

• Hydrogen Bond 100%
• Oxygenation 100%
• Crystal Structure 50%
• Isomerization 50%
• Revertant 50%
• Unspecific Monooxygenase 50%
• Biomimetics 50%
• Thiophene 50%

Chemistry

• Dioxygen 100%
• Hydrogen Bonding 50%
• Donor 50%
• Biomimetics 25%
• Crystal Structure 25%
• Density Functional Theory 25%
• Isomerization 25%
• N-Heterocyclic Carbene 25%
• Monooxygenase 25%
• Cyclic Ether 25%
• Multireference Method 25%
• Peptidylglycine 25%
• Acetonitrile 25%
• Thiophene 25%