Calix[4]arenes Linked to Multiple Bidentate N-Donors: Potential Ligands for Synthetic Modeling of Multinuclear Metalloenzymes

Douglas J.E. Spencer; Bryan J. Johnson; Brian J. Johnson; William B Tolman

doi:10.1021/ol025715g

Calix[4]arenes Linked to Multiple Bidentate N-Donors: Potential Ligands for Synthetic Modeling of Multinuclear Metalloenzymes

Douglas J.E. Spencer, Bryan J. Johnson, Brian J. Johnson, William B Tolman

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

(Matrix Presented) A series of calix[4]arenes incorporating three or four bidentate diamines or pyridylamines attached at the "upper rim" were synthesized via practical protocols. Proof of structure was obtained in one instance by X-ray crystallography. These molecules are designed for general use as ligands for the preparation of multinuclear active site models of metalloenzymes.

Original language	English (US)
Pages (from-to)	1391-1393
Number of pages	3
Journal	Organic Letters
Volume	4
Issue number	8
DOIs	https://doi.org/10.1021/ol025715g
State	Published - Apr 18 2002

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AU - Tolman, William B

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AB - (Matrix Presented) A series of calix[4]arenes incorporating three or four bidentate diamines or pyridylamines attached at the "upper rim" were synthesized via practical protocols. Proof of structure was obtained in one instance by X-ray crystallography. These molecules are designed for general use as ligands for the preparation of multinuclear active site models of metalloenzymes.

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Calix[4]arenes Linked to Multiple Bidentate N-Donors: Potential Ligands for Synthetic Modeling of Multinuclear Metalloenzymes

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