Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates

Ian Armitage; G. Dunsmore; L. D. Hall; A. G. Marshall

doi:10.1039/C29710001281

Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates

Ian Armitage
, G. Dunsmore
, L. D. Hall
, A. G. Marshall

Biochemistry, Molecular Biology, and Biophysics (TMED)

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

By varying the ligand concentration the bound chemical shift and the equilibrium constant for the binding of ligand to lanthanide may be determined; studies of tris(dipivalomethanato)europium(III) complexes show that n-propylamine is bound more strongly than is neopentanol.

Original language	English (US)
Pages (from-to)	1281-1282
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	20
DOIs	https://doi.org/10.1039/C29710001281
State	Published - 1971

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title = "Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates",

abstract = "By varying the ligand concentration the bound chemical shift and the equilibrium constant for the binding of ligand to lanthanide may be determined; studies of tris(dipivalomethanato)europium(III) complexes show that n-propylamine is bound more strongly than is neopentanol.",

author = "Ian Armitage and G. Dunsmore and Hall, \{L. D.\} and Marshall, \{A. G.\}",

year = "1971",

doi = "10.1039/C29710001281",

language = "English (US)",

pages = "1281--1282",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0577-6171",

publisher = "Royal Society of Chemistry",

number = "20",

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T1 - Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates

AU - Armitage, Ian

AU - Dunsmore, G.

AU - Hall, L. D.

AU - Marshall, A. G.

PY - 1971

Y1 - 1971

N2 - By varying the ligand concentration the bound chemical shift and the equilibrium constant for the binding of ligand to lanthanide may be determined; studies of tris(dipivalomethanato)europium(III) complexes show that n-propylamine is bound more strongly than is neopentanol.

AB - By varying the ligand concentration the bound chemical shift and the equilibrium constant for the binding of ligand to lanthanide may be determined; studies of tris(dipivalomethanato)europium(III) complexes show that n-propylamine is bound more strongly than is neopentanol.

UR - https://www.scopus.com/pages/publications/37049116413

UR - https://www.scopus.com/pages/publications/37049116413#tab=citedBy

U2 - 10.1039/C29710001281

DO - 10.1039/C29710001281

M3 - Article

AN - SCOPUS:37049116413

SN - 0577-6171

SP - 1281

EP - 1282

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 20

ER -

Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates

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