Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates

Ian Armitage; G. Dunsmore; L. D. Hall; A. G. Marshall

doi:10.1039/C29710001281

Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates

Ian Armitage, G. Dunsmore, L. D. Hall, A. G. Marshall

Biochemistry, Molecular Biology, and Biophysics (TMED)

Research output: Contribution to journal › Article › peer-review

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Abstract

By varying the ligand concentration the bound chemical shift and the equilibrium constant for the binding of ligand to lanthanide may be determined; studies of tris(dipivalomethanato)europium(III) complexes show that n-propylamine is bound more strongly than is neopentanol.

Original language	English (US)
Pages (from-to)	1281-1282
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	20
DOIs	https://doi.org/10.1039/C29710001281
State	Published - 1971

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title = "Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates",

abstract = "By varying the ligand concentration the bound chemical shift and the equilibrium constant for the binding of ligand to lanthanide may be determined; studies of tris(dipivalomethanato)europium(III) complexes show that n-propylamine is bound more strongly than is neopentanol.",

author = "Ian Armitage and G. Dunsmore and Hall, {L. D.} and Marshall, {A. G.}",

year = "1971",

doi = "10.1039/C29710001281",

language = "English (US)",

pages = "1281--1282",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0577-6171",

publisher = "Royal Society of Chemistry",

number = "20",

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T1 - Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates

AU - Armitage, Ian

AU - Dunsmore, G.

AU - Hall, L. D.

AU - Marshall, A. G.

PY - 1971

Y1 - 1971

N2 - By varying the ligand concentration the bound chemical shift and the equilibrium constant for the binding of ligand to lanthanide may be determined; studies of tris(dipivalomethanato)europium(III) complexes show that n-propylamine is bound more strongly than is neopentanol.

AB - By varying the ligand concentration the bound chemical shift and the equilibrium constant for the binding of ligand to lanthanide may be determined; studies of tris(dipivalomethanato)europium(III) complexes show that n-propylamine is bound more strongly than is neopentanol.

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U2 - 10.1039/C29710001281

DO - 10.1039/C29710001281

M3 - Article

AN - SCOPUS:37049116413

SN - 0577-6171

SP - 1281

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JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 20

ER -

Calculation of binding constants and bound chemical shifts for the association of lanthanide shift reagents with organic substrates

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