C-N bond hydrogenolysis of aniline and cyclohexylamine over TaO:X-Al2O3

Mark Bachrach, Tobin J. Marks, Justin M. Notestein

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

TaOx grafted onto Al2O3 is investigated for C-N bond cleavage of amines under H2 pressure. Heteroaromatics such as aniline are stoichiometrically denitrogenated at high temperature, while cyclohexylamine is catalytically denitrogenated. UV-visible and X-ray photoelectron spectroscopy indicate the formation of a stable Ta-N species in the former case.

Original languageEnglish (US)
Pages (from-to)6001-6004
Number of pages4
JournalNew Journal of Chemistry
Volume40
Issue number7
DOIs
StatePublished - Jan 1 2016

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