Broadening the scope of group 4 hydroamination catalysis using a tethered ureate ligand

Keyphrases

• Hydroamination 100%
• Ureate 100%
• Alkenes 66%
• Primary Amines 66%
• Secondary Amines 66%
• Chemoselective 33%
• Urea 33%
• Amines 33%
• Disubstituted 33%
• Alkynes 33%
• Functional Groups 33%
• Silane 33%
• Cyclization 33%
• Regioselectivity 33%
• Amides 33%
• Ether 33%
• Precatalyst 33%
• Catalyst System 33%
• Heteroatom 33%
• Screening Experiment 33%
• Alkyne Hydroamination 33%
• Intramolecular Hydroamination 33%
• Heteroaromatics 33%
• C3-alkylation 33%
• Zirconium Complexes 33%
• 7-membered Ring 33%
• Proligand 33%
• Anti-Markovnikov 33%
• Gem-Disubstituent Effect 33%
• Aminoalkenes 33%
• Intermolecular Hydroamination 33%

Chemistry

• Hydroamination 100%
• Alkene 33%
• Primary Amine 33%
• Secondary Amine 33%
• Alkyne 33%
• Chemoselectivity 16%
• Heteroatom 16%
• Zirconium 16%
• Carboxamide 16%
• pre-catalyst 16%
• C-alkylation 16%