Bispidine ligand effects on iron/hydrogen peroxide chemistry

Michael R. Bukowski, Peter Comba, Christian Limberg, Michael Merz, Lawrence Que, Tobias Wistuba

Research output: Contribution to journalArticlepeer-review

69 Scopus citations

Abstract

...and yet so different. Non-heme iron complexes catalyze the stereoselective oxidation of C-H and C=C bonds. Isomeric FeIII- η1-hydroperoxo and FeIII2-peroxo complexes (see picture), important intermediates in these reactions, were studied by EPR, resonance Raman, and UV/Vis spectroscopies.

Original languageEnglish (US)
Pages (from-to)1283-1287
Number of pages5
JournalAngewandte Chemie - International Edition
Volume43
Issue number10
DOIs
StatePublished - Feb 27 2004

Keywords

  • Coordination modes
  • Iron
  • Ligands
  • Stereochemistry

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