Bis(1,2,3,4-η4-anthracene)ferrate(1-): A paramagnetic homoleptic polyarene transition-metal anion

William W. Brennessel; Robert E. Jilek; John E. Ellis

doi:10.1002/anie.200701353

Bis(1,2,3,4-η⁴-anthracene)ferrate(1-): A paramagnetic homoleptic polyarene transition-metal anion

William W. Brennessel, Robert E. Jilek, John E. Ellis

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

59 Scopus citations

Abstract

(Figure Presented) Magnetic personalities: [Fe(η⁴-C ₁₄H₁₀)₂]^- is an unprecedented example of an anionic 17-electron homoleptic polyarene transition-metal complex. This species is the first isolable homoleptic polyarene iron complex. It provides "naked" atomic Fe^-1 in its reaction with 1,3-butadiene to yield the first structurally authenticated homoleptic bis(1,3-butadiene) metal complex, [Fe(η⁴-C₄H ₆)₂]^_ (see structure).

Original language	English (US)
Pages (from-to)	6132-6136
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	32
DOIs	https://doi.org/10.1002/anie.200701353
State	Published - 2007

Keywords

Arene ligands
Diene ligands
Iron
Negative-valent complexes
Sandwich complexes

Publisher link

10.1002/anie.200701353

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title = "Bis(1,2,3,4-η4-anthracene)ferrate(1-): A paramagnetic homoleptic polyarene transition-metal anion",

abstract = "(Figure Presented) Magnetic personalities: [Fe(η4-C 14H10)2]- is an unprecedented example of an anionic 17-electron homoleptic polyarene transition-metal complex. This species is the first isolable homoleptic polyarene iron complex. It provides {"}naked{"} atomic Fe-1 in its reaction with 1,3-butadiene to yield the first structurally authenticated homoleptic bis(1,3-butadiene) metal complex, [Fe(η4-C4H 6)2]_ (see structure).",

keywords = "Arene ligands, Diene ligands, Iron, Negative-valent complexes, Sandwich complexes",

author = "Brennessel, {William W.} and Jilek, {Robert E.} and Ellis, {John E.}",

year = "2007",

doi = "10.1002/anie.200701353",

language = "English (US)",

volume = "46",

pages = "6132--6136",

journal = "Angewandte Chemie - International Edition",

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}

TY - JOUR

T1 - Bis(1,2,3,4-η4-anthracene)ferrate(1-)

T2 - A paramagnetic homoleptic polyarene transition-metal anion

AU - Brennessel, William W.

AU - Jilek, Robert E.

AU - Ellis, John E.

PY - 2007

Y1 - 2007

N2 - (Figure Presented) Magnetic personalities: [Fe(η4-C 14H10)2]- is an unprecedented example of an anionic 17-electron homoleptic polyarene transition-metal complex. This species is the first isolable homoleptic polyarene iron complex. It provides "naked" atomic Fe-1 in its reaction with 1,3-butadiene to yield the first structurally authenticated homoleptic bis(1,3-butadiene) metal complex, [Fe(η4-C4H 6)2]_ (see structure).

AB - (Figure Presented) Magnetic personalities: [Fe(η4-C 14H10)2]- is an unprecedented example of an anionic 17-electron homoleptic polyarene transition-metal complex. This species is the first isolable homoleptic polyarene iron complex. It provides "naked" atomic Fe-1 in its reaction with 1,3-butadiene to yield the first structurally authenticated homoleptic bis(1,3-butadiene) metal complex, [Fe(η4-C4H 6)2]_ (see structure).

KW - Arene ligands

KW - Diene ligands

KW - Iron

KW - Negative-valent complexes

KW - Sandwich complexes

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