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Keyphrases
Non-heme Iron
100%
Biomimetic
100%
Hydroxylation
100%
Aryl
100%
Fe(II)
100%
Alkyl Hydroperoxides
100%
Ortho
50%
Fe(III)
50%
Arenes
50%
Acetonitrile
50%
Iron(III)
50%
Deuterium
33%
Higher Spin
33%
Phenyl
33%
UV-VIS Spectroscopy
33%
Homolytic
33%
Oxo-bridged
33%
Phenolate
33%
Low Temperature
16%
Amino Acids
16%
Dioxygen
16%
Reaction Time
16%
X Ray Diffraction
16%
Order of Magnitude
16%
Deuteration
16%
X-ray Crystallography
16%
Peroxide
16%
Hydroxylated
16%
Low Spin
16%
Tris(2-pyridylmethyl)amine
16%
Resonance Raman Spectroscopy
16%
Hydroxylase
16%
Metal Center
16%
Electrophilic
16%
Solvate
16%
1H nuclear Magnetic Resonance (1H NMR)
16%
EPR Spectroscopy
16%
Dichloromethane
16%
Oxoiron(IV)
16%
Oxoiron(IV) Complexes
16%
Pterin
16%
Tripodal Ligands
16%
Tetradentate
16%
Reactive Intermediates
16%
Hydroperoxides
16%
18O-labeling
16%
Monomeric Complex
16%
Bond Cleavage
16%
Product Complexity
16%
Transient Intermediates
16%
Mechanistic Evidence
16%
Aryl Substituents
16%
NIH Shift
16%
Tert-butyl Hydroperoxide (t-BHP)
16%
Propyl
16%
Methyl Substituent
16%
Alkoxy Radical
16%
2-methyl-1
16%
Chemistry
Biomimetics
100%
Alkyl Hydroperoxide
100%
hydroxylation
100%
Chemistry
40%
UV/VIS Spectroscopy
40%
Phenolate
40%
Acetonitrile
40%
dimer
40%
Deuterium
40%
EPR Spectroscopy
20%
Dioxygen
20%
1H NMR Spectroscopy
20%
Tris
20%
X-Ray Diffraction
20%
Reactive Intermediate
20%
Tert-Butyl Hydroperoxide
20%
Pterin
20%
X-Ray Crystallography
20%
Hydroperoxide
20%
Raman Spectrometry
20%
formation
20%
Amino Acid
20%