Bio-inspired arene cis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase

Yan Feng; Chun Yen Ke; Genqiang Xue; Larry Que

doi:10.1039/b817222f

Bio-inspired arene cis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase

Yan Feng
, Chun Yen Ke
, Genqiang Xue
, Larry Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

Reported in this paper is the first example of a biomimetic iron complex, ([Fe^II(TPA)(NCMe)₂]²⁺ (TPA = tris(2-pyridylmethyl)amine), that catalyses the cis-dihydroxylation of an aromatic double bond, mimicking the action of the non-haem iron enzyme naphthalene dioxygenase and shedding light on its possible mechanism of action.

Original language	English (US)
Pages (from-to)	50-52
Number of pages	3
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/b817222f
State	Published - 2009

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10.1039/b817222f

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AB - Reported in this paper is the first example of a biomimetic iron complex, ([FeII(TPA)(NCMe)2]2+ (TPA = tris(2-pyridylmethyl)amine), that catalyses the cis-dihydroxylation of an aromatic double bond, mimicking the action of the non-haem iron enzyme naphthalene dioxygenase and shedding light on its possible mechanism of action.

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Bio-inspired arene cis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase

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