Bi- and trimetallic rare-earth-palladium complexes ligated by phosphinoamides

Franziska Völcker; Felix M. Mück; Konstantinos D. Vogiatzis; Karin Fink; Peter W. Roesky

doi:10.1039/c5cc03944d

Bi- and trimetallic rare-earth-palladium complexes ligated by phosphinoamides

Franziska Völcker, Felix M. Mück, Konstantinos D. Vogiatzis, Karin Fink, Peter W. Roesky

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The synthesis of the heterometallic early-late 4d/4f bi- and trinuclear phosphinoamido Ln-Pd(0) complexes [(Ph₂PNHPh)Pd{μ-(Ph₂PNPh)}₃Ln(μ-Cl)Li(THF)₃] (Ln = Y, Lu) and [Li(THF)₄][{(Ph₂PNHPh)Pd}₂{μ-(Ph₂PNPh)}₄Ln] (Ln = Y, Lu) is described. The latter compounds are the first early-late trimetallic phosphinoamido complexes. Although the metal atoms are forced into close proximity by the phosphinoamido ligands, quantum chemical calculations show only weak metal-to-metal interactions.

Original language	English (US)
Pages (from-to)	11761-11764
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	59
DOIs	https://doi.org/10.1039/c5cc03944d
State	Published - Jul 28 2015

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry.

Publisher link

10.1039/c5cc03944d

Find It

Find It at U of M Libraries

Cite this

@article{b1db13f714ee4c9c90799d779fc739a4,

title = "Bi- and trimetallic rare-earth-palladium complexes ligated by phosphinoamides",

abstract = "The synthesis of the heterometallic early-late 4d/4f bi- and trinuclear phosphinoamido Ln-Pd(0) complexes [(Ph2PNHPh)Pd\{μ-(Ph2PNPh)\}3Ln(μ-Cl)Li(THF)3] (Ln = Y, Lu) and [Li(THF)4][\{(Ph2PNHPh)Pd\}2\{μ-(Ph2PNPh)\}4Ln] (Ln = Y, Lu) is described. The latter compounds are the first early-late trimetallic phosphinoamido complexes. Although the metal atoms are forced into close proximity by the phosphinoamido ligands, quantum chemical calculations show only weak metal-to-metal interactions.",

author = "Franziska V{\"o}lcker and M{\"u}ck, \{Felix M.\} and Vogiatzis, \{Konstantinos D.\} and Karin Fink and Roesky, \{Peter W.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

month = jul,

day = "28",

doi = "10.1039/c5cc03944d",

language = "English (US)",

volume = "51",

pages = "11761--11764",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "59",

}

TY - JOUR

T1 - Bi- and trimetallic rare-earth-palladium complexes ligated by phosphinoamides

AU - Völcker, Franziska

AU - Mück, Felix M.

AU - Vogiatzis, Konstantinos D.

AU - Fink, Karin

AU - Roesky, Peter W.

PY - 2015/7/28

Y1 - 2015/7/28

N2 - The synthesis of the heterometallic early-late 4d/4f bi- and trinuclear phosphinoamido Ln-Pd(0) complexes [(Ph2PNHPh)Pd{μ-(Ph2PNPh)}3Ln(μ-Cl)Li(THF)3] (Ln = Y, Lu) and [Li(THF)4][{(Ph2PNHPh)Pd}2{μ-(Ph2PNPh)}4Ln] (Ln = Y, Lu) is described. The latter compounds are the first early-late trimetallic phosphinoamido complexes. Although the metal atoms are forced into close proximity by the phosphinoamido ligands, quantum chemical calculations show only weak metal-to-metal interactions.

AB - The synthesis of the heterometallic early-late 4d/4f bi- and trinuclear phosphinoamido Ln-Pd(0) complexes [(Ph2PNHPh)Pd{μ-(Ph2PNPh)}3Ln(μ-Cl)Li(THF)3] (Ln = Y, Lu) and [Li(THF)4][{(Ph2PNHPh)Pd}2{μ-(Ph2PNPh)}4Ln] (Ln = Y, Lu) is described. The latter compounds are the first early-late trimetallic phosphinoamido complexes. Although the metal atoms are forced into close proximity by the phosphinoamido ligands, quantum chemical calculations show only weak metal-to-metal interactions.

UR - https://www.scopus.com/pages/publications/84936864571

UR - https://www.scopus.com/inward/citedby.url?scp=84936864571&partnerID=8YFLogxK

U2 - 10.1039/c5cc03944d

DO - 10.1039/c5cc03944d

M3 - Article

C2 - 26108472

AN - SCOPUS:84936864571

SN - 1359-7345

VL - 51

SP - 11761

EP - 11764

JO - Chemical Communications

JF - Chemical Communications

IS - 59

ER -

Bi- and trimetallic rare-earth-palladium complexes ligated by phosphinoamides

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Cite this