Abstract
Measurements of the transition energies of GaAsSb quantum well samples with different barrier configurations reveal that the conduction band offset of the coherently strained GaAs1-ySby/GaAs heterojunction grown on GaAs has a zero crossing at a Sb mole fraction of y=0.43±0.07. A type-I band alignment is formed for lower Sb mole fractions and a type-II band alignment is formed for higher Sb mole fractions. This occurs as a consequence of a considerable amount (58%) of the -1.58eV bandgap bowing being distributed to the conduction band. As a suitable active material for 1.3 μm emission, pseudomorphic GaAs0.643Sb0.357 grown on GaAs is determined to have a weak, 23±23 meV, type-I conduction band offset and a bandgap energy of 928±4 meV.
| Original language | English (US) |
|---|---|
| Article number | 195339 |
| Pages (from-to) | 1-8 |
| Number of pages | 8 |
| Journal | Physical Review B - Condensed Matter and Materials Physics |
| Volume | 70 |
| Issue number | 19 |
| DOIs | |
| State | Published - Nov 2004 |
| Externally published | Yes |
Bibliographical note
Funding Information:This work is partially supported by the National Science Foundation under Grant No. 0070125.
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