Axial coordination of carboxylate activates the non-heme FeIV=O unit

Jan Uwe Rohde; Lawrence Que

doi:10.1002/anie.200462631

Axial coordination of carboxylate activates the non-heme Fe^IV=O unit

Jan Uwe Rohde, Lawrence Que

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

91 Scopus citations

Abstract

(Chemical Equation Presented) Enhancing reactivity: A common feature of non-heme iron enzymes is the presence of carboxylate groups. An axial carboxylate group has been introduced trans to the oxo group of a non-heme oxoiron(IV) complex (see scheme). The coordination of carboxylate destabilizes the Fe^IV=O unit and activates it towards reaction with dihydroanthracene.

Original language	English (US)
Pages (from-to)	2255-2258
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	15
DOIs	https://doi.org/10.1002/anie.200462631
State	Published - Apr 8 2005

Keywords

Bioinorganic chemistry
Carboxylate ligands
High-valent compounds
Iron
Oxo ligands

Publisher link

10.1002/anie.200462631

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abstract = "(Chemical Equation Presented) Enhancing reactivity: A common feature of non-heme iron enzymes is the presence of carboxylate groups. An axial carboxylate group has been introduced trans to the oxo group of a non-heme oxoiron(IV) complex (see scheme). The coordination of carboxylate destabilizes the FeIV=O unit and activates it towards reaction with dihydroanthracene.",

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AU - Que, Lawrence

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AB - (Chemical Equation Presented) Enhancing reactivity: A common feature of non-heme iron enzymes is the presence of carboxylate groups. An axial carboxylate group has been introduced trans to the oxo group of a non-heme oxoiron(IV) complex (see scheme). The coordination of carboxylate destabilizes the FeIV=O unit and activates it towards reaction with dihydroanthracene.

KW - Bioinorganic chemistry

KW - Carboxylate ligands

KW - High-valent compounds

KW - Iron

KW - Oxo ligands

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