Au2Sx/CdS nanorods by cation exchange: Mechanistic insights into the competition between cation-exchange and metal ion reduction

Subhajit Kundu; Paromita Kundu; Gustaaf Van Tendeloo; N. Ravishankar

doi:10.1002/smll.201400524

Au₂S_x/CdS nanorods by cation exchange: Mechanistic insights into the competition between cation-exchange and metal ion reduction

Subhajit Kundu
, Paromita Kundu
, Gustaaf Van Tendeloo
, N. Ravishankar

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

(Figure Presented) It is well known that metals with higher electron affinity like Au tend to undergo reduction rather than cation-exchange. It is experimentally shown that under certain conditions cation-exchange is dominant over reduction. Thermodynamic calculation further consolidates the understanding and paves the way for better predictability of cation-exchange/reduction reactions for other systems.

Original language	English (US)
Pages (from-to)	3895-3900
Number of pages	6
Journal	Small
Volume	10
Issue number	19
DOIs	https://doi.org/10.1002/smll.201400524
State	Published - Oct 1 2014
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2014 Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords

Cation-exchange
Free energy
Heterostructures
Nucleation

Publisher link

10.1002/smll.201400524

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Cite this

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abstract = "(Figure Presented) It is well known that metals with higher electron affinity like Au tend to undergo reduction rather than cation-exchange. It is experimentally shown that under certain conditions cation-exchange is dominant over reduction. Thermodynamic calculation further consolidates the understanding and paves the way for better predictability of cation-exchange/reduction reactions for other systems.",

keywords = "Cation-exchange, Free energy, Heterostructures, Nucleation",

author = "Subhajit Kundu and Paromita Kundu and \{Van Tendeloo\}, Gustaaf and N. Ravishankar",

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AU - Kundu, Paromita

AU - Van Tendeloo, Gustaaf

AU - Ravishankar, N.

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Y1 - 2014/10/1

N2 - (Figure Presented) It is well known that metals with higher electron affinity like Au tend to undergo reduction rather than cation-exchange. It is experimentally shown that under certain conditions cation-exchange is dominant over reduction. Thermodynamic calculation further consolidates the understanding and paves the way for better predictability of cation-exchange/reduction reactions for other systems.

AB - (Figure Presented) It is well known that metals with higher electron affinity like Au tend to undergo reduction rather than cation-exchange. It is experimentally shown that under certain conditions cation-exchange is dominant over reduction. Thermodynamic calculation further consolidates the understanding and paves the way for better predictability of cation-exchange/reduction reactions for other systems.

KW - Cation-exchange

KW - Free energy

KW - Heterostructures

KW - Nucleation

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