TY - JOUR
T1 - Atmospheric volatile organic compound measurements during the Pittsburgh Air Quality Study
T2 - Results, interpretation, and quantification of primary and secondary contributions
AU - Millet, Dylan B.
AU - Donahue, Neil M.
AU - Pandis, Spyros N.
AU - Polidori, Andrea
AU - Stanier, Charles O.
AU - Turpin, Barbara J.
AU - Goldstein, Allen H.
N1 - Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.
PY - 2005
Y1 - 2005
N2 - Primary and secondary contributions to ambient levels of volatile organic compounds (VOCs) and aerosol organic carbon (OC) are determined using measurements at the Pittsburgh Air Quality Study (PAQS) during January-February and July-August 2002. Primary emission ratios for gas and aerosol species are defined by correlation with species of known origin, and contributions from primary and secondary/biogenic sources and from the regional background are then determined. Primary anthropogenic contributions to ambient levels of acetone, methylethylketone, and acetaldehyde were found to be 12-23% in winter and 2-10% in summer. Secondary production plus biogenic emissions accounted for 12-27% of the total mixing ratios for these compounds in winter and 26-34% in summer, with background concentrations accounting for the remainder. Using the same method, we determined that on average 16% of aerosol OC was secondary in origin during winter versus 37% during summer. Factor analysis of the VOC and aerosol data is used to define the dominant source types in the region for both seasons. Local automotive emissions were the strongest contributor to changes in atmospheric VOC concentrations; however, they did not significantly impact the aerosol species included in the factor analysis. We conclude that longer-range transport and industrial emissions were more important sources of aerosol during the study period. The VOC data are also used to characterize the photochemical state of the atmosphere in the region. The total measured OH loss rate was dominated by nonmethane hydrocarbons and CO (76% of the total) in winter and by isoprene, its oxidation products, and oxygenated VOCs (79% of the total) in summer, when production of secondary organic aerosol was highest.
AB - Primary and secondary contributions to ambient levels of volatile organic compounds (VOCs) and aerosol organic carbon (OC) are determined using measurements at the Pittsburgh Air Quality Study (PAQS) during January-February and July-August 2002. Primary emission ratios for gas and aerosol species are defined by correlation with species of known origin, and contributions from primary and secondary/biogenic sources and from the regional background are then determined. Primary anthropogenic contributions to ambient levels of acetone, methylethylketone, and acetaldehyde were found to be 12-23% in winter and 2-10% in summer. Secondary production plus biogenic emissions accounted for 12-27% of the total mixing ratios for these compounds in winter and 26-34% in summer, with background concentrations accounting for the remainder. Using the same method, we determined that on average 16% of aerosol OC was secondary in origin during winter versus 37% during summer. Factor analysis of the VOC and aerosol data is used to define the dominant source types in the region for both seasons. Local automotive emissions were the strongest contributor to changes in atmospheric VOC concentrations; however, they did not significantly impact the aerosol species included in the factor analysis. We conclude that longer-range transport and industrial emissions were more important sources of aerosol during the study period. The VOC data are also used to characterize the photochemical state of the atmosphere in the region. The total measured OH loss rate was dominated by nonmethane hydrocarbons and CO (76% of the total) in winter and by isoprene, its oxidation products, and oxygenated VOCs (79% of the total) in summer, when production of secondary organic aerosol was highest.
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U2 - 10.1029/2004JD004601
DO - 10.1029/2004JD004601
M3 - Article
AN - SCOPUS:30344471215
SN - 0148-0227
VL - 110
SP - 1
EP - 17
JO - Journal of Geophysical Research Atmospheres
JF - Journal of Geophysical Research Atmospheres
IS - 7
M1 - D07S07
ER -