Asymmetric synthesis of umuravumbolide1

M. Venkat Ram Reddy; John P. Rearick; Nyssa Hoch; P. Veeraraghavan Ramachandran

doi:10.1021/ol006583z

Asymmetric synthesis of umuravumbolide1

M. Venkat Ram Reddy
, John P. Rearick
, Nyssa Hoch
, P. Veeraraghavan Ramachandran

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

56 Scopus citations

Abstract

(equation presented) This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of α,β-acetylenic alcohols is also described.

Original language	English (US)
Pages (from-to)	19-20
Number of pages	2
Journal	Organic Letters
Volume	3
Issue number	1
DOIs	https://doi.org/10.1021/ol006583z
State	Published - Jan 11 2001

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@article{e7472e96b1e04f11a7ee7a3252ce1c7f,

title = "Asymmetric synthesis of umuravumbolide1",

abstract = "(equation presented) This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of α,β-acetylenic alcohols is also described.",

author = "\{Venkat Ram Reddy\}, M. and Rearick, \{John P.\} and Nyssa Hoch and \{Veeraraghavan Ramachandran\}, P.",

year = "2001",

month = jan,

day = "11",

doi = "10.1021/ol006583z",

language = "English (US)",

volume = "3",

pages = "19--20",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "1",

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TY - JOUR

T1 - Asymmetric synthesis of umuravumbolide1

AU - Venkat Ram Reddy, M.

AU - Rearick, John P.

AU - Hoch, Nyssa

AU - Veeraraghavan Ramachandran, P.

PY - 2001/1/11

Y1 - 2001/1/11

N2 - (equation presented) This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of α,β-acetylenic alcohols is also described.

AB - (equation presented) This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of α,β-acetylenic alcohols is also described.

UR - https://www.scopus.com/pages/publications/0035843312

UR - https://www.scopus.com/pages/publications/0035843312#tab=citedBy

U2 - 10.1021/ol006583z

DO - 10.1021/ol006583z

M3 - Article

C2 - 11429860

AN - SCOPUS:0035843312

SN - 1523-7060

VL - 3

SP - 19

EP - 20

JO - Organic Letters

JF - Organic Letters

IS - 1

ER -

Asymmetric synthesis of umuravumbolide1

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