Asymmetric synthesis of umuravumbolide1

M. Venkat Ram Reddy, John P. Rearick, Nyssa Hoch, P. Veeraraghavan Ramachandran

Research output: Contribution to journalArticlepeer-review

54 Scopus citations

Abstract

(equation presented) This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of α,β-acetylenic alcohols is also described.

Original languageEnglish (US)
Pages (from-to)19-20
Number of pages2
JournalOrganic Letters
Volume3
Issue number1
DOIs
StatePublished - Jan 11 2001

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