Abstract
Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal-metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen-carbon bonds.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 113-122 |
| Number of pages | 10 |
| Journal | Journal of Chemical Sciences |
| Volume | 123 |
| Issue number | 2 |
| DOIs | |
| State | Published - Mar 2011 |
| Externally published | Yes |
Keywords
- M-C bond cleavage
- Metallophilic
- Organochalcogen
- Secondary bonding intramolecular interaction
- Telluroxane
- Transmetallation
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