Aspects of secondary bonding intramolecular interaction in organomercury and organochalcogen derivatives

Sagar Sharma, Tapash Chakraborty, Kriti Srivastava, Harkesh B. Singh

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal-metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen-carbon bonds.

Original languageEnglish (US)
Pages (from-to)113-122
Number of pages10
JournalJournal of Chemical Sciences
Volume123
Issue number2
DOIs
StatePublished - Mar 2011

Keywords

  • M-C bond cleavage
  • Metallophilic
  • Organochalcogen
  • Secondary bonding intramolecular interaction
  • Telluroxane
  • Transmetallation

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