Aspects of secondary bonding intramolecular interaction in organomercury and organochalcogen derivatives

Sagar Sharma; Tapash Chakraborty; Kriti Srivastava; Harkesh B. Singh

doi:10.1007/s12039-011-0106-3

Aspects of secondary bonding intramolecular interaction in organomercury and organochalcogen derivatives

Sagar Sharma, Tapash Chakraborty, Kriti Srivastava, Harkesh B. Singh

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal-metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen-carbon bonds.

Original language	English (US)
Pages (from-to)	113-122
Number of pages	10
Journal	Journal of Chemical Sciences
Volume	123
Issue number	2
DOIs	https://doi.org/10.1007/s12039-011-0106-3
State	Published - Mar 2011
Externally published	Yes

Keywords

M-C bond cleavage
Metallophilic
Organochalcogen
Secondary bonding intramolecular interaction
Telluroxane
Transmetallation

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10.1007/s12039-011-0106-3

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abstract = "Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal-metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen-carbon bonds.",

keywords = "M-C bond cleavage, Metallophilic, Organochalcogen, Secondary bonding intramolecular interaction, Telluroxane, Transmetallation",

author = "Sagar Sharma and Tapash Chakraborty and Kriti Srivastava and Singh, {Harkesh B.}",

year = "2011",

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doi = "10.1007/s12039-011-0106-3",

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journal = "Journal of Chemical Sciences",

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T1 - Aspects of secondary bonding intramolecular interaction in organomercury and organochalcogen derivatives

AU - Sharma, Sagar

AU - Chakraborty, Tapash

AU - Srivastava, Kriti

AU - Singh, Harkesh B.

PY - 2011/3

Y1 - 2011/3

N2 - Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal-metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen-carbon bonds.

AB - Recent trends in the area of intramolecularly coordinated organomercury and organochalcogens derivatives are reviewed. Intramolecular coordination in organomercury derivatives facilitates the formation of mercurametallamacrocycle and leads to novel metal-metal interaction with closed shell ions. It also plays a key role in stabilizing telluroxanes as well as in the activation of chalcogen-carbon bonds.

KW - M-C bond cleavage

KW - Metallophilic

KW - Organochalcogen

KW - Secondary bonding intramolecular interaction

KW - Telluroxane

KW - Transmetallation

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JO - Journal of Chemical Sciences

JF - Journal of Chemical Sciences

IS - 2

ER -

Aspects of secondary bonding intramolecular interaction in organomercury and organochalcogen derivatives

Abstract

Keywords

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