Aqueous oxidation of sulfonamide antibiotics: Aromatic nucleophilic substitution of an aniline radical cation

Keyphrases

• Radical Cation 100%
• Aniline 100%
• Aqueous Oxidation 100%
• Sulfonamide Antibiotics 100%
• Aromatic nucleophilic Substitution 100%
• Aquatic Environment 66%
• NMR Spectroscopy 33%
• Extrusion 33%
• Reaction Pathway 33%
• Model Calculation 33%
• Oxidation Products 33%
• Density Functional Calculations 33%
• Pyrimidine 33%
• Nucleophile 33%
• One-electron Oxidation 33%
• Low Barrier 33%
• Nucleophilic Attack 33%
• Sulfadiazine 33%
• Para-position 33%
• Sulfur Dioxide 33%
• Organic Micropollutants 33%
• Protonation State 33%
• Detailed Reaction Mechanism 33%
• Transient Absorption Spectroscopy 33%
• Quantum Chemical Modeling 33%

Chemistry

• Radical Cation 100%
• Sulfonamide Antibiotic 100%
• Nucleophilic Aromatic Substitution 100%
• Sulfur Dioxide 100%
• NMR Spectroscopy 50%
• Density Functional Theory 50%
• Sulfonamide 50%
• Detailed Reaction Mechanisms 50%
• Nucleophile 50%
• Absorption Spectroscopy 50%
• Sulfadiazine 50%