Anhydride-Additive-Free Nickel-Catalyzed Deoxygenation of Carboxylic Acids to Olefins

Alex John; Marc A. Hillmyer; William B. Tolman

doi:10.1021/acs.organomet.6b00940

Anhydride-Additive-Free Nickel-Catalyzed Deoxygenation of Carboxylic Acids to Olefins

Alex John
, Marc A. Hillmyer
, William B. Tolman

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

A nickel-catalyzed route for direct, anhydride-additive-free deoxygenation of fatty acids to the corresponding olefins has been developed. The transformation is catalyzed by simple nickel salts of the type NiX₂ (X = halide, acetate, acetylacetonate), uses PPh₃ as a stoichiometric reductant, and exhibits selectivity for generation of linear α-olefin products.

Original language	English (US)
Pages (from-to)	506-509
Number of pages	4
Journal	Organometallics
Volume	36
Issue number	3
DOIs	https://doi.org/10.1021/acs.organomet.6b00940
State	Published - Feb 13 2017

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© 2017 American Chemical Society.

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abstract = "A nickel-catalyzed route for direct, anhydride-additive-free deoxygenation of fatty acids to the corresponding olefins has been developed. The transformation is catalyzed by simple nickel salts of the type NiX2 (X = halide, acetate, acetylacetonate), uses PPh3 as a stoichiometric reductant, and exhibits selectivity for generation of linear α-olefin products.",

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Y1 - 2017/2/13

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AB - A nickel-catalyzed route for direct, anhydride-additive-free deoxygenation of fatty acids to the corresponding olefins has been developed. The transformation is catalyzed by simple nickel salts of the type NiX2 (X = halide, acetate, acetylacetonate), uses PPh3 as a stoichiometric reductant, and exhibits selectivity for generation of linear α-olefin products.

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UR - https://www.scopus.com/pages/publications/85017513618#tab=citedBy

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ER -

Anhydride-Additive-Free Nickel-Catalyzed Deoxygenation of Carboxylic Acids to Olefins

Abstract

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