An inverted and more oxidizing isomer of [FeIV(O)(tmc)- (NCCH3)]2+

Kallol Ray, Jason England, Adam T. Fiedler, Marlène Martinho, Eckard Münck, Lawrence Que

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

(Chemical Equation Presented) Oxoferryl gymnastics: The oxo and CH 3CN ligands in 1-NCCH3 can swap positions in the presence of iodosobenzene and tetrafluoroborate anion leading to the generation of a more reactive isomer 2. This conversion is proposed to take place via an activated FeIV unit (1a) or a transient dioxoiron(VI) species (1b).

Original languageEnglish (US)
Pages (from-to)8068-8071
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number42
DOIs
StatePublished - Oct 6 2008

Keywords

  • Bioinorganic chemistry
  • Coordination modes
  • Cyclam
  • High-valent compounds
  • Nonheme iron complexes

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