An improved vinylalumination procedure replacing HMPA with NMO for the hydroalumination of α-acetylenic esters and ketones

P. Veeraraghavan Ramachandran, M. Venkat Ram Reddy, Michael T. Rudd

Research output: Contribution to journalArticlepeer-review

47 Scopus citations

Abstract

Replacing carcinogenic HMPA with NMO, a higher yielding, enviornmentally benign procedure for the vinylalumination of carbonyl compounds with [α-(ethoxycarbonyl)vinyl]diisobutylaluminium and its β-methyl or -phenyl analogs, as well as [α-(acetyl)vinyl]diisobutylaluminium has been developed.

Original languageEnglish (US)
Pages (from-to)1979-1980
Number of pages2
JournalChemical Communications
Issue number19
StatePublished - Oct 7 1999

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