An extremely mild 3-aza-claisen reaction. 2. New conditions and the rearrangement of α-heteroatom substituted amides

M. A. Walters; A. B. Hoem; H. R. Arcand; A. D. Hegeman; C. S. McDonough

doi:10.1016/S0040-4039(00)60316-7

An extremely mild 3-aza-claisen reaction. 2. New conditions and the rearrangement of α-heteroatom substituted amides

M. A. Walters
, A. B. Hoem
, H. R. Arcand
, A. D. Hegeman
, C. S. McDonough

Horticultural Science

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Several new and potentially useful reaction conditions for the 3-aza-Claisen rearrangement of N-allyl amides have been developed. These new conditions have been successfully applied to the rearrangement of α-heteroatom substituted species forming α-amino nitriles and protected cyanohydrins as products.

Original language	English (US)
Pages (from-to)	1453-1456
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	9
DOIs	https://doi.org/10.1016/S0040-4039(00)60316-7
State	Published - Feb 26 1993

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title = "An extremely mild 3-aza-claisen reaction. 2. New conditions and the rearrangement of α-heteroatom substituted amides",

abstract = "Several new and potentially useful reaction conditions for the 3-aza-Claisen rearrangement of N-allyl amides have been developed. These new conditions have been successfully applied to the rearrangement of α-heteroatom substituted species forming α-amino nitriles and protected cyanohydrins as products.",

author = "Walters, \{M. A.\} and Hoem, \{A. B.\} and Arcand, \{H. R.\} and Hegeman, \{A. D.\} and McDonough, \{C. S.\}",

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AU - Walters, M. A.

AU - Hoem, A. B.

AU - Arcand, H. R.

AU - Hegeman, A. D.

AU - McDonough, C. S.

PY - 1993/2/26

Y1 - 1993/2/26

N2 - Several new and potentially useful reaction conditions for the 3-aza-Claisen rearrangement of N-allyl amides have been developed. These new conditions have been successfully applied to the rearrangement of α-heteroatom substituted species forming α-amino nitriles and protected cyanohydrins as products.

AB - Several new and potentially useful reaction conditions for the 3-aza-Claisen rearrangement of N-allyl amides have been developed. These new conditions have been successfully applied to the rearrangement of α-heteroatom substituted species forming α-amino nitriles and protected cyanohydrins as products.

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UR - https://www.scopus.com/pages/publications/0027405465#tab=citedBy

U2 - 10.1016/S0040-4039(00)60316-7

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AN - SCOPUS:0027405465

SN - 0040-4039

VL - 34

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 9

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An extremely mild 3-aza-claisen reaction. 2. New conditions and the rearrangement of α-heteroatom substituted amides

Abstract

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