An extremely mild 3-aza-claisen reaction. 2. New conditions and the rearrangement of α-heteroatom substituted amides

M. A. Walters, A. B. Hoem, H. R. Arcand, A. D. Hegeman, C. S. McDonough

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

Several new and potentially useful reaction conditions for the 3-aza-Claisen rearrangement of N-allyl amides have been developed. These new conditions have been successfully applied to the rearrangement of α-heteroatom substituted species forming α-amino nitriles and protected cyanohydrins as products.

Original languageEnglish (US)
Pages (from-to)1453-1456
Number of pages4
JournalTetrahedron Letters
Volume34
Issue number9
DOIs
StatePublished - Feb 26 1993

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