An anomaly in the isotopomer shift of the hyperfine spectrum of LiI

J. Cederberg; J. Nichol; E. Frodermann; H. Tollerud; G. Hilk; J. Buysman; W. Kleiber; M. Bongard; J. Ward; K. Huber; T. Khanna; J. Randolph; D. Nitz

doi:10.1063/1.2052588

An anomaly in the isotopomer shift of the hyperfine spectrum of LiI

J. Cederberg
, J. Nichol
, E. Frodermann
, H. Tollerud
, G. Hilk
, J. Buysman
, W. Kleiber
, M. Bongard
, J. Ward
, K. Huber
, T. Khanna
, J. Randolph
, D. Nitz

Physics and Astronomy (Twin Cities)

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A high-precision examination of the hyperfine spectrum of Li6 I in comparison with Li7 I shows a shift in the iodine nuclear electric quadrupole moment that cannot be accounted for by a model in which the electric field gradient at the iodine site is assumed to depend only upon the internuclear distance between Li and I. The other hyperfine interactions are consistent between the two isotopomers, including the previously reported electric hexadecapole interaction of the iodine nucleus.

Original language	English (US)
Article number	134321
Journal	Journal of Chemical Physics
Volume	123
Issue number	13
DOIs	https://doi.org/10.1063/1.2052588
State	Published - Oct 3 2005

Bibliographical note

Funding Information:
The authors would like to thank the National Science Foundation for supporting this work as well as the Hardy Research Fellowship and St. Olaf College.

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10.1063/1.2052588

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title = "An anomaly in the isotopomer shift of the hyperfine spectrum of LiI",

abstract = "A high-precision examination of the hyperfine spectrum of Li6 I in comparison with Li7 I shows a shift in the iodine nuclear electric quadrupole moment that cannot be accounted for by a model in which the electric field gradient at the iodine site is assumed to depend only upon the internuclear distance between Li and I. The other hyperfine interactions are consistent between the two isotopomers, including the previously reported electric hexadecapole interaction of the iodine nucleus.",

author = "J. Cederberg and J. Nichol and E. Frodermann and H. Tollerud and G. Hilk and J. Buysman and W. Kleiber and M. Bongard and J. Ward and K. Huber and T. Khanna and J. Randolph and D. Nitz",

note = "Funding Information: The authors would like to thank the National Science Foundation for supporting this work as well as the Hardy Research Fellowship and St. Olaf College.",

year = "2005",

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doi = "10.1063/1.2052588",

language = "English (US)",

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T1 - An anomaly in the isotopomer shift of the hyperfine spectrum of LiI

AU - Cederberg, J.

AU - Nichol, J.

AU - Frodermann, E.

AU - Tollerud, H.

AU - Hilk, G.

AU - Buysman, J.

AU - Kleiber, W.

AU - Bongard, M.

AU - Ward, J.

AU - Huber, K.

AU - Khanna, T.

AU - Randolph, J.

AU - Nitz, D.

N1 - Funding Information: The authors would like to thank the National Science Foundation for supporting this work as well as the Hardy Research Fellowship and St. Olaf College.

PY - 2005/10/3

Y1 - 2005/10/3

N2 - A high-precision examination of the hyperfine spectrum of Li6 I in comparison with Li7 I shows a shift in the iodine nuclear electric quadrupole moment that cannot be accounted for by a model in which the electric field gradient at the iodine site is assumed to depend only upon the internuclear distance between Li and I. The other hyperfine interactions are consistent between the two isotopomers, including the previously reported electric hexadecapole interaction of the iodine nucleus.

AB - A high-precision examination of the hyperfine spectrum of Li6 I in comparison with Li7 I shows a shift in the iodine nuclear electric quadrupole moment that cannot be accounted for by a model in which the electric field gradient at the iodine site is assumed to depend only upon the internuclear distance between Li and I. The other hyperfine interactions are consistent between the two isotopomers, including the previously reported electric hexadecapole interaction of the iodine nucleus.

UR - https://www.scopus.com/pages/publications/26444539822

UR - https://www.scopus.com/pages/publications/26444539822#tab=citedBy

U2 - 10.1063/1.2052588

DO - 10.1063/1.2052588

M3 - Article

AN - SCOPUS:26444539822

SN - 0021-9606

VL - 123

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 13

M1 - 134321

ER -

An anomaly in the isotopomer shift of the hyperfine spectrum of LiI

Abstract

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