Amidinato- and guanidinato-cobalt(I) Complexes: Characterization of exceptionally short Co-Co interactions

Cameron Jones; Christian Schulten; Richard P. Rose; Andreas Stasch; Simon Aldridge; William D. Woodul; Keith S. Murray; Boujemaa Moubaraki; Marcin Brynda; Giovanni La Macchia; Laura Gagliardi

doi:10.1002/anie.200900780

Amidinato- and guanidinato-cobalt(I) Complexes: Characterization of exceptionally short Co-Co interactions

Cameron Jones, Christian Schulten, Richard P. Rose, Andreas Stasch, Simon Aldridge, William D. Woodul, Keith S. Murray, Boujemaa Moubaraki, Marcin Brynda, Giovanni La Macchia, Laura Gagliardi

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

121 Scopus citations

Abstract

CoCo loco! Ligand-bridged dimers (see picture) with the shortest known Co-Co interactions are the first amidinato and guanidinato cobalt(I) complexes. The nature of the interactions has been probed by magnetic and theoretical investigations, and has been shown to be multiconfigurational. Preliminary reactivity studies of the complexes have also been carried out.

Original language	English (US)
Pages (from-to)	7406-7410
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	40
DOIs	https://doi.org/10.1002/anie.200900780
State	Published - Sep 21 2009

Keywords

Cobalt
Magnetic properties
Metalmetal interactions
N ligands

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10.1002/anie.200900780

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abstract = "CoCo loco! Ligand-bridged dimers (see picture) with the shortest known Co-Co interactions are the first amidinato and guanidinato cobalt(I) complexes. The nature of the interactions has been probed by magnetic and theoretical investigations, and has been shown to be multiconfigurational. Preliminary reactivity studies of the complexes have also been carried out.",

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T1 - Amidinato- and guanidinato-cobalt(I) Complexes

T2 - Characterization of exceptionally short Co-Co interactions

AU - Jones, Cameron

AU - Schulten, Christian

AU - Rose, Richard P.

AU - Stasch, Andreas

AU - Aldridge, Simon

AU - Woodul, William D.

AU - Murray, Keith S.

AU - Moubaraki, Boujemaa

AU - Brynda, Marcin

AU - La Macchia, Giovanni

AU - Gagliardi, Laura

PY - 2009/9/21

Y1 - 2009/9/21

N2 - CoCo loco! Ligand-bridged dimers (see picture) with the shortest known Co-Co interactions are the first amidinato and guanidinato cobalt(I) complexes. The nature of the interactions has been probed by magnetic and theoretical investigations, and has been shown to be multiconfigurational. Preliminary reactivity studies of the complexes have also been carried out.

AB - CoCo loco! Ligand-bridged dimers (see picture) with the shortest known Co-Co interactions are the first amidinato and guanidinato cobalt(I) complexes. The nature of the interactions has been probed by magnetic and theoretical investigations, and has been shown to be multiconfigurational. Preliminary reactivity studies of the complexes have also been carried out.

KW - Cobalt

KW - Magnetic properties

KW - Metalmetal interactions

KW - N ligands

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 40

ER -

Amidinato- and guanidinato-cobalt(I) Complexes: Characterization of exceptionally short Co-Co interactions

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