Ambient temperature solid polymer electrolyte devices

P. S.S. Prasad; M. Z.A. Munshi; B. B. Owens; W. H. Smyrl

doi:10.1016/0167-2738(90)90162-K

Ambient temperature solid polymer electrolyte devices

P. S.S. Prasad, M. Z.A. Munshi, B. B. Owens, W. H. Smyrl

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

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Abstract

Poly(ethylene oxide) based solid polymer electrolytes with lithium bis-perfluoro-acyl-imide and lithium bis-perfluoro-sulfonylimide plasticizer salts have been investigated by complex impedance analysis, differential scanning calorimetry and electrochemical performance in the Li/V₆O₁₃ electrode couple environment. Poly(ethylene oxide)-poly(ethylene glycol) based composite polymer blends with LiCF₃SO₃ salt were also studied as possible ambient temperature electrolytes. A third group of polymer electrolytes based on lithium salts doped into non-aqueous gels were found to possess an ionic conductivity of 4.5×10^-4 S cm at 22°C. The material was used as an electrolyte in the fabrication of a thin film electrochemical cell (6.5 cm² area) with the Li/V₆O₁₃ electrode couple. Preliminary results indicated a good reversibility, but interfacial polarization was significant.

Original language	English (US)
Pages (from-to)	959-963
Number of pages	5
Journal	Solid State Ionics
Volume	40-41
Issue number	PART 2
DOIs	https://doi.org/10.1016/0167-2738(90)90162-K
State	Published - Aug 1990

Bibliographical note

Funding Information:
The work is financially supported in part by the Office of Naval Research (ONR) and Defence Advanced Research Projects Agency (DARPA), U.S.A.

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title = "Ambient temperature solid polymer electrolyte devices",

abstract = "Poly(ethylene oxide) based solid polymer electrolytes with lithium bis-perfluoro-acyl-imide and lithium bis-perfluoro-sulfonylimide plasticizer salts have been investigated by complex impedance analysis, differential scanning calorimetry and electrochemical performance in the Li/V6O13 electrode couple environment. Poly(ethylene oxide)-poly(ethylene glycol) based composite polymer blends with LiCF3SO3 salt were also studied as possible ambient temperature electrolytes. A third group of polymer electrolytes based on lithium salts doped into non-aqueous gels were found to possess an ionic conductivity of 4.5×10-4 S cm at 22°C. The material was used as an electrolyte in the fabrication of a thin film electrochemical cell (6.5 cm2 area) with the Li/V6O13 electrode couple. Preliminary results indicated a good reversibility, but interfacial polarization was significant.",

author = "Prasad, {P. S.S.} and Munshi, {M. Z.A.} and Owens, {B. B.} and Smyrl, {W. H.}",

note = "Funding Information: The work is financially supported in part by the Office of Naval Research (ONR) and Defence Advanced Research Projects Agency (DARPA), U.S.A.",

year = "1990",

month = aug,

doi = "10.1016/0167-2738(90)90162-K",

language = "English (US)",

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T1 - Ambient temperature solid polymer electrolyte devices

AU - Prasad, P. S.S.

AU - Munshi, M. Z.A.

AU - Owens, B. B.

AU - Smyrl, W. H.

N1 - Funding Information: The work is financially supported in part by the Office of Naval Research (ONR) and Defence Advanced Research Projects Agency (DARPA), U.S.A.

PY - 1990/8

Y1 - 1990/8

N2 - Poly(ethylene oxide) based solid polymer electrolytes with lithium bis-perfluoro-acyl-imide and lithium bis-perfluoro-sulfonylimide plasticizer salts have been investigated by complex impedance analysis, differential scanning calorimetry and electrochemical performance in the Li/V6O13 electrode couple environment. Poly(ethylene oxide)-poly(ethylene glycol) based composite polymer blends with LiCF3SO3 salt were also studied as possible ambient temperature electrolytes. A third group of polymer electrolytes based on lithium salts doped into non-aqueous gels were found to possess an ionic conductivity of 4.5×10-4 S cm at 22°C. The material was used as an electrolyte in the fabrication of a thin film electrochemical cell (6.5 cm2 area) with the Li/V6O13 electrode couple. Preliminary results indicated a good reversibility, but interfacial polarization was significant.

AB - Poly(ethylene oxide) based solid polymer electrolytes with lithium bis-perfluoro-acyl-imide and lithium bis-perfluoro-sulfonylimide plasticizer salts have been investigated by complex impedance analysis, differential scanning calorimetry and electrochemical performance in the Li/V6O13 electrode couple environment. Poly(ethylene oxide)-poly(ethylene glycol) based composite polymer blends with LiCF3SO3 salt were also studied as possible ambient temperature electrolytes. A third group of polymer electrolytes based on lithium salts doped into non-aqueous gels were found to possess an ionic conductivity of 4.5×10-4 S cm at 22°C. The material was used as an electrolyte in the fabrication of a thin film electrochemical cell (6.5 cm2 area) with the Li/V6O13 electrode couple. Preliminary results indicated a good reversibility, but interfacial polarization was significant.

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DO - 10.1016/0167-2738(90)90162-K

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VL - 40-41

SP - 959

EP - 963

JO - Solid State Ionics

JF - Solid State Ionics

IS - PART 2

ER -

Ambient temperature solid polymer electrolyte devices

Abstract

Bibliographical note

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