Allylmalonate as an activator subunit for the initiation of relay ring-closing metathesis reactions

Thomas R. Hoye; Junha Jeon; Manomi A. Tennakoon

doi:10.1002/anie.201005044

Allylmalonate as an activator subunit for the initiation of relay ring-closing metathesis reactions

Thomas R. Hoye, Junha Jeon, Manomi A. Tennakoon

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Passing the baton: The relay ring-closing metathesis (RRCM) reaction of complex polyenes 1 has been studied. Several relay subunits (T) were examined and many did not sufficiently activate the RRCM. An allylmalonate-containing relay subunit solved this problem, and efficiently lead to the diene 2. TIPS=triisopropylsilyl.

Original language	English (US)
Pages (from-to)	2141-2143
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	9
DOIs	https://doi.org/10.1002/anie.201005044
State	Published - Feb 25 2011

Keywords

cyclization
metathesis
reaction mechanisms
ruthenium

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10.1002/anie.201005044

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title = "Allylmalonate as an activator subunit for the initiation of relay ring-closing metathesis reactions",

abstract = "Passing the baton: The relay ring-closing metathesis (RRCM) reaction of complex polyenes 1 has been studied. Several relay subunits (T) were examined and many did not sufficiently activate the RRCM. An allylmalonate-containing relay subunit solved this problem, and efficiently lead to the diene 2. TIPS=triisopropylsilyl.",

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T1 - Allylmalonate as an activator subunit for the initiation of relay ring-closing metathesis reactions

AU - Hoye, Thomas R.

AU - Jeon, Junha

AU - Tennakoon, Manomi A.

PY - 2011/2/25

Y1 - 2011/2/25

N2 - Passing the baton: The relay ring-closing metathesis (RRCM) reaction of complex polyenes 1 has been studied. Several relay subunits (T) were examined and many did not sufficiently activate the RRCM. An allylmalonate-containing relay subunit solved this problem, and efficiently lead to the diene 2. TIPS=triisopropylsilyl.

AB - Passing the baton: The relay ring-closing metathesis (RRCM) reaction of complex polyenes 1 has been studied. Several relay subunits (T) were examined and many did not sufficiently activate the RRCM. An allylmalonate-containing relay subunit solved this problem, and efficiently lead to the diene 2. TIPS=triisopropylsilyl.

KW - cyclization

KW - metathesis

KW - reaction mechanisms

KW - ruthenium

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U2 - 10.1002/anie.201005044

DO - 10.1002/anie.201005044

M3 - Article

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AN - SCOPUS:79951894844

SN - 1433-7851

VL - 50

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

Allylmalonate as an activator subunit for the initiation of relay ring-closing metathesis reactions

Abstract

Keywords

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