Allylic substitutions catalyzed by miscellaneous metals

Jeanne Marie Begouin, Johannes E.M.N. Klein, Daniel Weickmann, Bernd Plietker

Research output: Chapter in Book/Report/Conference proceedingChapter

37 Scopus citations

Abstract

Allylic substitutions catalyzed by miscellaneous metals have recently been uncovered as useful alternatives to the established corresponding transition metal catalyzed transformations. In particular, the interesting regioselectivity course of the allylic substitutions is of synthetic interest. In this chapter, we summarize the most recent findings in the field of group 8-10 metal (Fe, Ru, Co, Rh, Ni, Pt) catalyzed substitutions with a strong emphasis on the substrate range and the regioselectivity.

Original languageEnglish (US)
Title of host publicationTransition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis
EditorsUli Kazmaier
Pages269-320
Number of pages52
DOIs
StatePublished - 2012
Externally publishedYes

Publication series

NameTopics in Organometallic Chemistry
Volume38
ISSN (Print)1436-6002

Keywords

  • Allylic Substitution
  • Group 8-10
  • Miscellaneous Metals
  • Regioselectivity
  • Substrate Range

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