Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN2COCR2CH2C^C(CH2)n2CH=CH2]

Thomas R Hoye; Christopher J. Dinsmore; Douglas S. Johnson; Paul F. Korkowski

doi:10.1021/jo00302a010

Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN₂COCR₂CH₂C^C(CH₂)_n2CH=CH₂]

Thomas R Hoye
, Christopher J. Dinsmore
, Douglas S. Johnson
, Paul F. Korkowski

Research output: Contribution to journal › Article › peer-review

90 Scopus citations

Abstract

: The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3.

Original language	English (US)
Pages (from-to)	4518-4520
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	55
Issue number	15
DOIs	https://doi.org/10.1021/jo00302a010
State	Published - 1990

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10.1021/jo00302a010

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@article{a4521b9bae8748939f93a41148f98a82,

title = "Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN2COCR2CH2C\textasciicircum{}C(CH2)n2CH=CH2]",

abstract = ": The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3.",

author = "Hoye, \{Thomas R\} and Dinsmore, \{Christopher J.\} and Johnson, \{Douglas S.\} and Korkowski, \{Paul F.\}",

year = "1990",

doi = "10.1021/jo00302a010",

language = "English (US)",

volume = "55",

pages = "4518--4520",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN2COCR2CH2C^C(CH2)n2CH=CH2]

AU - Hoye, Thomas R

AU - Dinsmore, Christopher J.

AU - Johnson, Douglas S.

AU - Korkowski, Paul F.

PY - 1990

Y1 - 1990

N2 - : The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3.

AB - : The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3.

UR - https://www.scopus.com/pages/publications/0001371890

UR - https://www.scopus.com/pages/publications/0001371890#tab=citedBy

U2 - 10.1021/jo00302a010

DO - 10.1021/jo00302a010

M3 - Article

AN - SCOPUS:0001371890

SN - 0022-3263

VL - 55

SP - 4518

EP - 4520

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 15

ER -

Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN₂COCR₂CH₂C^C(CH₂)_n2CH=CH₂]

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