Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN2COCR2CH2C^C(CH2)n2CH=CH2]

Thomas R Hoye; Christopher J. Dinsmore; Douglas S. Johnson; Paul F. Korkowski

doi:10.1021/jo00302a010

Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN₂COCR₂CH₂C^C(CH₂)_n2CH=CH₂]

Thomas R Hoye, Christopher J. Dinsmore, Douglas S. Johnson, Paul F. Korkowski

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

89 Scopus citations

Abstract

: The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3.

Original language	English (US)
Pages (from-to)	4518-4520
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	55
Issue number	15
DOIs	https://doi.org/10.1021/jo00302a010
State	Published - Jan 1 1990

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10.1021/jo00302a010

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title = "Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN2COCR2CH2C^C(CH2)n2CH=CH2]",

abstract = ": The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3.",

author = "Hoye, {Thomas R} and Dinsmore, {Christopher J.} and Johnson, {Douglas S.} and Korkowski, {Paul F.}",

year = "1990",

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doi = "10.1021/jo00302a010",

language = "English (US)",

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journal = "Journal of Organic Chemistry",

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AU - Hoye, Thomas R

AU - Dinsmore, Christopher J.

AU - Johnson, Douglas S.

AU - Korkowski, Paul F.

PY - 1990/1/1

Y1 - 1990/1/1

N2 - : The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3.

AB - : The title substrates react with a variety of metal catalysts to give metal-dependent product arrays (including tricyclic cyclopropanes and others formally arising from the vinylogous a-keto carbene 3.

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JO - Journal of Organic Chemistry

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IS - 15

ER -

Alkyne Insertion Reactions of Metal-Carbenes Derived from Enynyl a-Diazo Ketones [RCN₂COCR₂CH₂C^C(CH₂)_n2CH=CH₂]

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