Alkyltechnetium Oxides: First Examples and Reactions

Wolfgang A. Herrmann, Roger Alberto, Paul Kiprof, Franz Baumgärtner

Research output: Contribution to journalArticle

43 Scopus citations

Abstract

A “diagonal relationship” between technetium(VII) and osmium(VIII) can be proposed based on the properties of the newly synthesized title compounds. Like the valence‐isoelectronic OsO4, MeTcO3 adds olefins to form metallacycles (→cis‐diols), whereas the formally analogous MeReO3 epoxidates olefins in the presence of H2O2. This difference is presumably due to the oxidizing strength of TcVII being much greater than that of ReVII.

Original languageEnglish (US)
Pages (from-to)189-191
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume29
Issue number2
DOIs
StatePublished - Feb 1990

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