Acid precipitation and its influence upon aquatic ecosystems--an overview

The impact of acid precipitation reflects a usually deleterious balance between good and bad effects which may lead to serious and sometimes extreme degradation of aquatic as well as terrestrial ecosystems, particularly around metal smelters. Addition of H ions as H2SO4, HNO3, and HCl can alter and impoverish the species composition of biotic communities, and lead to severe leaching of beneficial metal cations such as Ca from ecosystems. Heavy metals and other trace elements which accompany acid precipitation may reach toxic levels, particularly where acid fallout leaches additional amounts from the soil into streams and lakes. Complex and often toxic hydrocarbons also comprise a little known organic component of acid precipitation.Alternatively, acid precipitation usually is enriched in plant nutrients such as nitrate- and ammonia-nitrogen, K, Ca, and S; and at certain concentrations some of the associated trace elements may also be beneficial. Moreover the initial effect of soil leaching by acid fallout may be to enrich aquatic ecosystems in metal cations such as Ca.Basic materials in air pollution, biogenic NH3 from the soil, dust fall from arid regions, and soils rich in adsorbed metal cations or in carbonates may neutralize some of the harmful effects of acid precipitation upon ecosystems. However, associated heavy metals, other trace elements, and toxic hydrocarbons may still constitute serious problems in many environments.