ABC-type miktoarm star terpolymers accessed by H-bonding driven supramolecular self-assembly

Ozcan Altintas; David Schulze-Suenninghausen; Burkhard Luy; Christopher Barner-Kowollik

doi:10.1016/j.eurpolymj.2014.04.006

ABC-type miktoarm star terpolymers accessed by H-bonding driven supramolecular self-assembly

Ozcan Altintas, David Schulze-Suenninghausen, Burkhard Luy, Christopher Barner-Kowollik

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A supramolecular ABC-type miktoarm star polymer was prepared using a Hamilton wedge (HW) mid-chain functionalized polyethylene glycol-b-polystyrene (PEG-HW-PS) block copolymer and an α-cyanuric acid (CA) chain-end functional linear homopolymer poly-(n-butylacrylate) (CA-PnBA). The PEG-HW-PS element prepared via a combination of atom transfer radical polymerization (ATRP) and copper-catalyzed azide alkyne cycloaddition (CuAAC) (M_n = 13,700 g mol^-1, PDI = 1.04). The CA-PnBA strand was synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization (M_n = 11,300 g mol^-1, PDI = 1.06). The quantitative formation of a well-defined supramolecular ABC-type miktoarm star polymer was unambiguously proven via proton nuclear magnetic resonance (¹H NMR) spectroscopy, diffusion ordered NMR spectroscopy (DOSY) and dynamic light scattering (DLS) analyses.

Original language	English (US)
Pages (from-to)	409-417
Number of pages	9
Journal	European Polymer Journal
Volume	62
DOIs	https://doi.org/10.1016/j.eurpolymj.2014.04.006
State	Published - Feb 2015

Bibliographical note

Funding Information:
C.B.-K. is grateful for continued support from the Karlsruhe Institute of Technology (KIT) in the context of the Helmholtz BIF program. B.L. acknowledges funding by the Deutsche Forschungsgemeinschaft (DFG LU 835/8-1, research group FOR 934, and DFG instrument facility Pro 2 NMR) and the Helmholtz BioInterfaces program.

Publisher Copyright:
© 2014 Elsevier Ltd. All rights reserved.

Keywords

DLS
DOSY
Hydrogenbonding
Miktoarms Star Polymers
Supramolecular Architectures

Publisher link

10.1016/j.eurpolymj.2014.04.006

Find It

Find It at U of M Libraries

Cite this

@article{efa1d0bb7afd4983855987793bbc724a,

title = "ABC-type miktoarm star terpolymers accessed by H-bonding driven supramolecular self-assembly",

abstract = "A supramolecular ABC-type miktoarm star polymer was prepared using a Hamilton wedge (HW) mid-chain functionalized polyethylene glycol-b-polystyrene (PEG-HW-PS) block copolymer and an α-cyanuric acid (CA) chain-end functional linear homopolymer poly-(n-butylacrylate) (CA-PnBA). The PEG-HW-PS element prepared via a combination of atom transfer radical polymerization (ATRP) and copper-catalyzed azide alkyne cycloaddition (CuAAC) (Mn = 13,700 g mol-1, PDI = 1.04). The CA-PnBA strand was synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization (Mn = 11,300 g mol-1, PDI = 1.06). The quantitative formation of a well-defined supramolecular ABC-type miktoarm star polymer was unambiguously proven via proton nuclear magnetic resonance (1H NMR) spectroscopy, diffusion ordered NMR spectroscopy (DOSY) and dynamic light scattering (DLS) analyses.",

keywords = "DLS, DOSY, Hydrogenbonding, Miktoarms Star Polymers, Supramolecular Architectures",

author = "Ozcan Altintas and David Schulze-Suenninghausen and Burkhard Luy and Christopher Barner-Kowollik",

note = "Funding Information: C.B.-K. is grateful for continued support from the Karlsruhe Institute of Technology (KIT) in the context of the Helmholtz BIF program. B.L. acknowledges funding by the Deutsche Forschungsgemeinschaft (DFG LU 835/8-1, research group FOR 934, and DFG instrument facility Pro 2 NMR) and the Helmholtz BioInterfaces program. Publisher Copyright: {\textcopyright} 2014 Elsevier Ltd. All rights reserved.",

year = "2015",

month = feb,

doi = "10.1016/j.eurpolymj.2014.04.006",

language = "English (US)",

volume = "62",

pages = "409--417",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - ABC-type miktoarm star terpolymers accessed by H-bonding driven supramolecular self-assembly

AU - Altintas, Ozcan

AU - Schulze-Suenninghausen, David

AU - Luy, Burkhard

AU - Barner-Kowollik, Christopher

N1 - Funding Information: C.B.-K. is grateful for continued support from the Karlsruhe Institute of Technology (KIT) in the context of the Helmholtz BIF program. B.L. acknowledges funding by the Deutsche Forschungsgemeinschaft (DFG LU 835/8-1, research group FOR 934, and DFG instrument facility Pro 2 NMR) and the Helmholtz BioInterfaces program. Publisher Copyright: © 2014 Elsevier Ltd. All rights reserved.

PY - 2015/2

Y1 - 2015/2

N2 - A supramolecular ABC-type miktoarm star polymer was prepared using a Hamilton wedge (HW) mid-chain functionalized polyethylene glycol-b-polystyrene (PEG-HW-PS) block copolymer and an α-cyanuric acid (CA) chain-end functional linear homopolymer poly-(n-butylacrylate) (CA-PnBA). The PEG-HW-PS element prepared via a combination of atom transfer radical polymerization (ATRP) and copper-catalyzed azide alkyne cycloaddition (CuAAC) (Mn = 13,700 g mol-1, PDI = 1.04). The CA-PnBA strand was synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization (Mn = 11,300 g mol-1, PDI = 1.06). The quantitative formation of a well-defined supramolecular ABC-type miktoarm star polymer was unambiguously proven via proton nuclear magnetic resonance (1H NMR) spectroscopy, diffusion ordered NMR spectroscopy (DOSY) and dynamic light scattering (DLS) analyses.

AB - A supramolecular ABC-type miktoarm star polymer was prepared using a Hamilton wedge (HW) mid-chain functionalized polyethylene glycol-b-polystyrene (PEG-HW-PS) block copolymer and an α-cyanuric acid (CA) chain-end functional linear homopolymer poly-(n-butylacrylate) (CA-PnBA). The PEG-HW-PS element prepared via a combination of atom transfer radical polymerization (ATRP) and copper-catalyzed azide alkyne cycloaddition (CuAAC) (Mn = 13,700 g mol-1, PDI = 1.04). The CA-PnBA strand was synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization (Mn = 11,300 g mol-1, PDI = 1.06). The quantitative formation of a well-defined supramolecular ABC-type miktoarm star polymer was unambiguously proven via proton nuclear magnetic resonance (1H NMR) spectroscopy, diffusion ordered NMR spectroscopy (DOSY) and dynamic light scattering (DLS) analyses.

KW - DLS

KW - DOSY

KW - Hydrogenbonding

KW - Miktoarms Star Polymers

KW - Supramolecular Architectures

UR - http://www.scopus.com/inward/record.url?scp=84919652876&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84919652876&partnerID=8YFLogxK

U2 - 10.1016/j.eurpolymj.2014.04.006

DO - 10.1016/j.eurpolymj.2014.04.006

M3 - Article

AN - SCOPUS:84919652876

SN - 0014-3057

VL - 62

SP - 409

EP - 417

JO - European Polymer Journal

JF - European Polymer Journal

ER -

ABC-type miktoarm star terpolymers accessed by H-bonding driven supramolecular self-assembly

Abstract

Bibliographical note

Keywords

Publisher link

Find It

Other files and links

Fingerprint

Cite this