A synthetic precedent for the [Fe^IV₂(μ-O) ₂] diamond core proposed for methane monooxygenase intermediate Q

Keyphrases

• Methane 100%
• Methane Monooxygenase 100%
• Mssbauer 100%
• Diamond Core 100%
• Scatterer 100%
• Diiron 50%
• Structure Analysis 50%
• Valence 50%
• Doublet 50%
• Extended X-ray Absorption Fine Structure (EXAFS) 50%
• Resonance Raman 50%
• Hydroxylation 50%
• Raman Studies 50%
• Soluble Methane Monooxygenase 50%
• C-H Bond 50%
• Spectroscopic Evidence 50%
• Downshifting 50%
• 18O-labeling 50%
• MeCN 50%
• Vibration Mode 50%
• Visible Spectrum 50%
• Quadrupole 50%
• Synthetic Enzyme Complex 50%
• Oxidizing Species 50%
• Iron(IV) 50%
• Deep-red 50%
• Bulk Electrolysis 50%
• Red Complex 50%
• Antiferromagnetically Coupled 50%

Chemistry

• Methane 100%
• Monooxygenase 100%
• Red 25%
• Quadrupole 25%
• Bulk Electrolysis 25%
• formation 25%
• hydroxylation 25%
• Visible Spectrum 25%

Earth and Planetary Sciences

• Methane 100%
• Fine Structure 25%
• Quadrupole 25%
• Visible Spectrum 25%
• Vibration Mode 25%
• Hydrogen Bond 25%
• Iron 25%