A synthetic model of Hg(ii) sequestration

Julie A. Viehweg; Sarah M. Stamps; Jennifer J. Dertinger; Robert L. Green; Katherine E. Harris; Raymond J. Butcher; Erica J. Andriole; J. C. Poutsma; Steven M. Berry; Deborah C. Bebout

doi:10.1039/c000002g

A synthetic model of Hg(ii) sequestration

Julie A. Viehweg
, Sarah M. Stamps
, Jennifer J. Dertinger
, Robert L. Green
, Katherine E. Harris
, Raymond J. Butcher
, Erica J. Andriole
, J. C. Poutsma
, Steven M. Berry
, Deborah C. Bebout

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg₅(L)₆](ClO₄) ₄·toluene (2) with a bicyclo[3.3.3] Hg₅S ₆ core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of 2 by ESI-MS revealed elaborate speciation involving [Hg _nL_n+1(ClO₄)_n-2]⁺, [Hg_nL_n(ClO₄)_n-1]⁺ and [Hg_nL_n-1(ClO₄)_n]⁺ ion families.

Original language	English (US)
Pages (from-to)	3174-3176
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	13
DOIs	https://doi.org/10.1039/c000002g
State	Published - 2010

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10.1039/c000002g

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title = "A synthetic model of Hg(ii) sequestration",

abstract = "Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg5(L)6](ClO4) 4·toluene (2) with a bicyclo[3.3.3] Hg5S 6 core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of 2 by ESI-MS revealed elaborate speciation involving [Hg nLn+1(ClO4)n-2]+, [HgnLn(ClO4)n-1]+ and [HgnLn-1(ClO4)n]+ ion families.",

author = "Viehweg, \{Julie A.\} and Stamps, \{Sarah M.\} and Dertinger, \{Jennifer J.\} and Green, \{Robert L.\} and Harris, \{Katherine E.\} and Butcher, \{Raymond J.\} and Andriole, \{Erica J.\} and Poutsma, \{J. C.\} and Berry, \{Steven M.\} and Bebout, \{Deborah C.\}",

year = "2010",

doi = "10.1039/c000002g",

language = "English (US)",

volume = "39",

pages = "3174--3176",

journal = "Dalton Transactions",

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TY - JOUR

T1 - A synthetic model of Hg(ii) sequestration

AU - Viehweg, Julie A.

AU - Stamps, Sarah M.

AU - Dertinger, Jennifer J.

AU - Green, Robert L.

AU - Harris, Katherine E.

AU - Butcher, Raymond J.

AU - Andriole, Erica J.

AU - Poutsma, J. C.

AU - Berry, Steven M.

AU - Bebout, Deborah C.

PY - 2010

Y1 - 2010

N2 - Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg5(L)6](ClO4) 4·toluene (2) with a bicyclo[3.3.3] Hg5S 6 core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of 2 by ESI-MS revealed elaborate speciation involving [Hg nLn+1(ClO4)n-2]+, [HgnLn(ClO4)n-1]+ and [HgnLn-1(ClO4)n]+ ion families.

AB - Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg5(L)6](ClO4) 4·toluene (2) with a bicyclo[3.3.3] Hg5S 6 core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of 2 by ESI-MS revealed elaborate speciation involving [Hg nLn+1(ClO4)n-2]+, [HgnLn(ClO4)n-1]+ and [HgnLn-1(ClO4)n]+ ion families.

UR - https://www.scopus.com/pages/publications/77949535165

UR - https://www.scopus.com/pages/publications/77949535165#tab=citedBy

U2 - 10.1039/c000002g

DO - 10.1039/c000002g

M3 - Article

C2 - 20449444

AN - SCOPUS:77949535165

SN - 1477-9226

VL - 39

SP - 3174

EP - 3176

JO - Dalton Transactions

JF - Dalton Transactions

IS - 13

ER -

A synthetic model of Hg(ii) sequestration

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