A synthetic model of Hg(ii) sequestration

Julie A. Viehweg; Sarah M. Stamps; Jennifer J. Dertinger; Robert L. Green; Katherine E. Harris; Raymond J. Butcher; Erica J. Andriole; J. C. Poutsma; Steven M. Berry; Deborah C. Bebout

doi:10.1039/c000002g

A synthetic model of Hg(ii) sequestration

Julie A. Viehweg, Sarah M. Stamps, Jennifer J. Dertinger, Robert L. Green, Katherine E. Harris, Raymond J. Butcher, Erica J. Andriole, J. C. Poutsma, Steven M. Berry, Deborah C. Bebout

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg₅(L)₆](ClO₄) ₄·toluene (2) with a bicyclo[3.3.3] Hg₅S ₆ core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of 2 by ESI-MS revealed elaborate speciation involving [Hg _nL_n+1(ClO₄)_n-2]⁺, [Hg_nL_n(ClO₄)_n-1]⁺ and [Hg_nL_n-1(ClO₄)_n]⁺ ion families.

Original language	English (US)
Pages (from-to)	3174-3176
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	13
DOIs	https://doi.org/10.1039/c000002g
State	Published - 2010

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title = "A synthetic model of Hg(ii) sequestration",

abstract = "Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg5(L)6](ClO4) 4·toluene (2) with a bicyclo[3.3.3] Hg5S 6 core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of 2 by ESI-MS revealed elaborate speciation involving [Hg nLn+1(ClO4)n-2]+, [HgnLn(ClO4)n-1]+ and [HgnLn-1(ClO4)n]+ ion families.",

author = "Viehweg, {Julie A.} and Stamps, {Sarah M.} and Dertinger, {Jennifer J.} and Green, {Robert L.} and Harris, {Katherine E.} and Butcher, {Raymond J.} and Andriole, {Erica J.} and Poutsma, {J. C.} and Berry, {Steven M.} and Bebout, {Deborah C.}",

year = "2010",

doi = "10.1039/c000002g",

language = "English (US)",

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pages = "3174--3176",

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T1 - A synthetic model of Hg(ii) sequestration

AU - Viehweg, Julie A.

AU - Stamps, Sarah M.

AU - Dertinger, Jennifer J.

AU - Green, Robert L.

AU - Harris, Katherine E.

AU - Butcher, Raymond J.

AU - Andriole, Erica J.

AU - Poutsma, J. C.

AU - Berry, Steven M.

AU - Bebout, Deborah C.

PY - 2010

Y1 - 2010

N2 - Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg5(L)6](ClO4) 4·toluene (2) with a bicyclo[3.3.3] Hg5S 6 core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of 2 by ESI-MS revealed elaborate speciation involving [Hg nLn+1(ClO4)n-2]+, [HgnLn(ClO4)n-1]+ and [HgnLn-1(ClO4)n]+ ion families.

AB - Tridentate ligand N-(2-pyridylmethyl)-N-(2-(ethylthiolato)amine (L) forms the novel complex [Hg5(L)6](ClO4) 4·toluene (2) with a bicyclo[3.3.3] Hg5S 6 core and 4-, 5- and 6-coordinate metal centers; characterization of a solution of 2 by ESI-MS revealed elaborate speciation involving [Hg nLn+1(ClO4)n-2]+, [HgnLn(ClO4)n-1]+ and [HgnLn-1(ClO4)n]+ ion families.

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DO - 10.1039/c000002g

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JF - Dalton Transactions

IS - 13

ER -

A synthetic model of Hg(ii) sequestration

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